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Nickel-oxide films are prepared by rf sputtering, and their electrochromic properties are investigated. Sputtering atmosphere used is an Ar-02 mixture. The films obtained can be electrochemically colored and bleached reversibly in an 1-N NaOH solution, and are colored anodically. Colored film is dark brown, and bleached one is colorless and transparent. Maximum coloration efficiency obtained is 36 cm2/C at a wavelength of 640 nm. Coloration efficiency depends on total pressure of sputtering atmosphere, but is independent of oxygen content in the atmosphere.
Shoji Yamada,Tatsuo Yoshioka,Masatoshi Miyashita,Kazuo Urabe, andMichihiko Kitao
"Electrochromic Behavior Of Hydrated Nickel-Oxide Films Prepared By Rf Sputtering", Proc. SPIE 1016, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VII, (6 March 1989); https://doi.org/10.1117/12.949911
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Shoji Yamada, Tatsuo Yoshioka, Masatoshi Miyashita, Kazuo Urabe, Michihiko Kitao, "Electrochromic Behavior Of Hydrated Nickel-Oxide Films Prepared By Rf Sputtering," Proc. SPIE 1016, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VII, (6 March 1989); https://doi.org/10.1117/12.949911