Paper
18 April 2017 Enhancement of electrocatalytic activity of octahedral Au@Pt core-shell nanoparticles by the surface plasmon excitation
Tatsuya Kameyama, Kentaro Sato, Tsukasa Torimoto
Author Affiliations +
Abstract
Octahedral Au-core Pt-shell (Au@Pt) nanoparticles were successfully prepared via a galvanic replacement of Cu monolayer underpotentially deposited on Au core with a Pt monolayer. The visible light irradiation to Au@Pt nanoparticles-immobilized electrodes enlarged a cathodic current of oxygen reduction reaction (ORR), suggesting that the electrocatalytic activity of Pt shell layer was enhanced by the photoexcitation of localized surface plasmon resonance peak of octahedral Au-core particles.
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Tatsuya Kameyama, Kentaro Sato, and Tsukasa Torimoto "Enhancement of electrocatalytic activity of octahedral Au@Pt core-shell nanoparticles by the surface plasmon excitation", Proc. SPIE 10252, Optical Manipulation Conference, 102521E (18 April 2017); https://doi.org/10.1117/12.2274899
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KEYWORDS
Nanoparticles

Gold

Platinum

Surface plasmons

Copper

Metals

Oxygen

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