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1 December 1989Vibrational Circular Dichroism Of Simple Chiral Molecules In The Gas Phase
Mid-infrared FTIR vibrational circular dichroism (VCD) of two exceptionally simple chiral three-membered ring molecules with C2 symmetry, (S,S)-oxirane-2,3-2H2 and (S,S)-cyclo-propane-1,2-2H2, have been obtained in the gas phase at 1 and 4 cm-1; resolution. The signs and relative intensities of the prominent VCD bands can be understood in terms of coupled C*H or C*D motions.
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T. B. Freedman, K. M. Spencer, C. McCarthy, S. J. Cianciosi, J. E. Baldwin, L. A. Nafie, J. A. Moore, J. M. Schwab, "Vibrational Circular Dichroism Of Simple Chiral Molecules In The Gas Phase," Proc. SPIE 1145, 7th Intl Conf on Fourier Transform Spectroscopy, (1 December 1989); https://doi.org/10.1117/12.969457