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Electrochromic crystalline W03 films which exhibit reversible metal-insulator transitions associated with lithium intercalation have been produced by an ion assisted deposition technique at substrate temperatures below 100°C. Electrochemical insertion of lithium in these films has resulted in a near infra-red reflection greater than 50 % .
F. O. Arntz,R. B. Goldner,B. Morel, andT. E. Haas
"Electrochromic Crystalline WO3 Films Prepared At Ambient Temperature By Ion Assisted Deposition", Proc. SPIE 1149, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VIII, (12 December 1989); https://doi.org/10.1117/12.962165
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F. O. Arntz, R. B. Goldner, B. Morel, T. E. Haas, "Electrochromic Crystalline WO3 Films Prepared At Ambient Temperature By Ion Assisted Deposition," Proc. SPIE 1149, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VIII, (12 December 1989); https://doi.org/10.1117/12.962165