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Efficient second-harmonic generation (SHG) was recently observed in
centrosymmetric doped glass f'ibrest'2. Two processes are important for
forming gratings in doped fibres, namely, the excitation of dopant
defects, and the creation and alignment of permanent dipoles in the fibre
core. Positively and negatively charged color centers are assumed to be
generated owing to two 3- or higher-order-photon absorption. Electric dipoles
can be created within strings of interconnected dopant defects
only3. It seems very likely that the dopant-defect strings are dominantly
oriented along the fibre due to the layer structure of dopant distribution
and the drawing process.
Pavel Chmela
"Self-organized quasi-phase-matched second harmonic generation in isotropic optical fibers", Proc. SPIE 1319, Optics in Complex Systems, (1 July 1990); https://doi.org/10.1117/12.34929
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Pavel Chmela, "Self-organized quasi-phase-matched second harmonic generation in isotropic optical fibers," Proc. SPIE 1319, Optics in Complex Systems, (1 July 1990); https://doi.org/10.1117/12.34929