Paper
12 December 2024 Preparation and structural characterization of VO2(B) and VO2(M) and investigation of their phase transition properties
Xinyu Song, Yue Liu, Chun Du, Shifeng Wang
Author Affiliations +
Proceedings Volume 13419, Tenth International Conference on Energy Materials and Electrical Engineering (ICEMEE 2024); 134193E (2024) https://doi.org/10.1117/12.3050741
Event: Tenth International Conference on Energy Materials and Electrical Engineering (ICEMEE 2024), 2024, Lhasa, China
Abstract
Due to its unique phase transition properties, vanadium dioxide (VO2) has attracted significant attention in smart window applications. However, VO2 currently has some shortcomings in the phase transition field, mainly including the uncontrollability of the phase transition process, insufficient crystallinity, and weak bond strength. Therefore, this study prepared M-phase VO2 with high crystallinity through annealing treatment, significantly enhancing the bond strength between vanadium and oxygen atoms, thus improving the material's stability. This enhanced stability reduces energy barriers during the phase transition, making the transition more controllable and reversible. The prepared VO2(M) exhibits a distinct endothermic peak at 67.40°C, with a peak heat flow of 0.59W/g. The results indicate that M-phase VO2 prepared through simple annealing treatment is highly suitable for applications requiring efficient phase change materials, overcoming the shortcomings of traditional VO2 materials in the phase transition field.
(2024) Published by SPIE. Downloading of the abstract is permitted for personal use only.
Xinyu Song, Yue Liu, Chun Du, and Shifeng Wang "Preparation and structural characterization of VO2(B) and VO2(M) and investigation of their phase transition properties", Proc. SPIE 13419, Tenth International Conference on Energy Materials and Electrical Engineering (ICEMEE 2024), 134193E (12 December 2024); https://doi.org/10.1117/12.3050741
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KEYWORDS
Vanadium

Crystals

Oxygen

Chemical species

Carbon

Scanning electron microscopy

Diffraction

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