Intrazeolite carbonyl metal chemistry: in-situ diffuse-reflectance infrared Fourier transform investigation

H. Boulet-Desgrousilliers; C. P. Bremard; Christophe Depecker; P. Legrand

doi:10.1117/12.56369

1 March 1992 Intrazeolite carbonyl metal chemistry: in-situ diffuse-reflectance infrared Fourier transform investigation

H. Boulet-Desgrousilliers, C. P. Bremard, Christophe Depecker, P. Legrand

Author Affiliations +

Proceedings Volume 1575, 8th Intl Conf on Fourier Transform Spectroscopy; (1992) https://doi.org/10.1117/12.56369
Event: Eighth International Conference on Fourier Transform Spectroscopy, 1991, Lubeck-Travemunde, Germany

Abstract

Diffuse Reflectance Infrared Fourier Transform Spectroscopic (DRIFTS) investigations indicate that under thermal activation, the coadsorption, by vapor-phase loading of benzene in the Na85%/X faujasite-type zeolite leads to the grafted Mo(CO3 moiety, whereas (n6-C6H6) Mo(CO)3 is obtained in Na55Y; no reaction is observed in the dealuminated Y* zeolite before the desorption on both benzene and Mo(CO)6.

Citation Download Citation

H. Boulet-Desgrousilliers, C. P. Bremard, Christophe Depecker, and P. Legrand "Intrazeolite carbonyl metal chemistry: in-situ diffuse-reflectance infrared Fourier transform investigation", Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); https://doi.org/10.1117/12.56369

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