Possibility of a "lithium glass" state appearance in the Li3Sc2-xFex(PO4)3 superionic solid solutions

Vladimir I. Michailov; Sergei E. Sigaryov; Vladimir G. Terziev

doi:10.1117/12.50215

1 November 1991 Possibility of a "lithium glass" state appearance in the Li₃Sc_2-xFe_x(PO₄)₃ superionic solid solutions

Vladimir I. Michailov, Sergei E. Sigaryov, Vladimir G. Terziev

Proceedings Volume 1590, Submolecular Glass Chemistry and Physics; (1991) https://doi.org/10.1117/12.50215
Event: OE Fiber, 1991, Boston, MA, United States

Abstract

For the Li3Sc2-xFex(PO4)3 superionic solid solutions it is shown that dynamic disorder of lithium ions observing at room temperature transforms into static disorder under cooling down to the liquid helium temperature. So, a glassy state in the lithium sublattice is suggested by analogy with "protonic glasses" in the ADP-RDP, KDP-ADP, and similar systems.

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Vladimir I. Michailov, Sergei E. Sigaryov, and Vladimir G. Terziev "Possibility of a "lithium glass" state appearance in the Li₃Sc_2-xFe_x(PO₄)₃ superionic solid solutions", Proc. SPIE 1590, Submolecular Glass Chemistry and Physics, (1 November 1991); https://doi.org/10.1117/12.50215

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