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Faraday rotator glasses with high Verdet constants are used for optical isolators and sensors. Based on the Tb2O3 -B2O3-Al2O3- SiO2 system and the effect of each component on glass formation, glass compositions were selected for development of new Faraday rotator glasses. Devitrification of Tb-glass was studied by microscopic morphology to establish the production process. Dispersion of Verdet constant and the influence of Tb3+ concentration on Verdet constant were investigated. Special technology was utilized for production of platinum-free glass. The quenching process is necessary to obtain crystal-free glass. Three kinds of Faraday rotator glass with higher Verdet constant than that of M16 have been developed. The higher Verdet constant glass is possible to obtain.
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Yasi Jiang, Michael J. Myers, Daniel L. Rhonehouse, "High Verdet constant Faraday rotator glasses," Proc. SPIE 1761, Damage to Space Optics, and Properties and Characteristics of Optical Glass, (11 January 1993); https://doi.org/10.1117/12.138933