Electrochemical properties of the newly synthesized poly(ferrocenyl dialkylsilane) polymers

My Tranh Nguyen; Arthur F. Diaz; Viacheslav V. Dement'ev; Hemant Sharma; Keith Pannell

doi:10.1117/12.151150

27 August 1993 Electrochemical properties of the newly synthesized poly(ferrocenyl dialkylsilane) polymers

My Tranh Nguyen, Arthur F. Diaz, Viacheslav V. Dement'ev, Hemant Sharma, Keith Pannell

Proceedings Volume 1910, Electroluminescent Materials, Devices, and Large-Screen Displays; (1993) https://doi.org/10.1117/12.151150
Event: IS&T/SPIE's Symposium on Electronic Imaging: Science and Technology, 1993, San Jose, CA, United States

Abstract

We have synthesized and characterized several poly(ferrocenyl dialkylsilane) polymers. The solutions and films of these polymers showed two reversible and stable redox reactions when cycled in organic electrolytes between 0.0 and 1.0 V (vs Ag/AgCl reference electrode). Their electrochemical behavior depends on the size of the alkyl substituents and the silane bridge between the ferrocene units for the (alpha) , (beta) diferrocenyl oligosilane. In addition, these newly synthesized polymers are thermally stable up to 400 degree(s)C. These poly(ferrocenyl dialkylsilane) polymers are potential candidates for use as the counter electrode or in the electrolyte component in electrochromic and electroluminescence display devices.

Citation Download Citation

My Tranh Nguyen, Arthur F. Diaz, Viacheslav V. Dement'ev, Hemant Sharma, and Keith Pannell "Electrochemical properties of the newly synthesized poly(ferrocenyl dialkylsilane) polymers", Proc. SPIE 1910, Electroluminescent Materials, Devices, and Large-Screen Displays, (27 August 1993); https://doi.org/10.1117/12.151150

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