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Thin-film Y-Ba-Cu-O Josephson junctions were fabricated with a photolithographic method. The junctions showed clear Shapiro steps under 94GHz irradiation. Harmonic mixing up to the number 55 was observed at a temperature of 77K and a frequency of 94GHz.
Y. Yasuoka
"Harmonic mixing in high-Tc YbCo Josephson junctions at 94 GHz", Proc. SPIE 1929, 17th International Conference on Infrared and Millimeter Waves, 19290D (14 December 1992); https://doi.org/10.1117/12.2298130
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Y. Yasuoka, "Harmonic mixing in high-Tc YbCo Josephson junctions at 94 GHz," Proc. SPIE 1929, 17th International Conference on Infrared and Millimeter Waves, 19290D (14 December 1992); https://doi.org/10.1117/12.2298130