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31 January 1994 Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl β-D-galactopyranoside
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Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166635
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada
Abstract
Low temperature measurements have been successfully applied to study the H-bond network in methyl-(beta) -D-galactopyranoside in the crystalline phase. Deuterium exchange experiments were required to get insight into vibrational coupling of the OH groups in the chain. Wavenumber-temperature coefficients may be used to characterize the O- H(DOT)(DOT)(DOT)O bonds. The effect of deuterium exchange on H-bond cooperativity is recognized in the OH stretching absorption at approximately 3360 cm-1 and the corresponding OD.
© (1994) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Bert Lutz, Marjan Olthof, Hendrik J. Luinge, and John H. van der Maas "Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl β-D-galactopyranoside", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); https://doi.org/10.1117/12.166635
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