Kinetic modeling of the reactions between F2 and the perfluoroalkyl iodides

Ernest A. Dorko; E. A. Walters; Daniel E. Johnson

doi:10.1117/12.172704

1 June 1994 Kinetic modeling of the reactions between F₂ and the perfluoroalkyl iodides

Ernest A. Dorko, E. A. Walters, Daniel E. Johnson

Proceedings Volume 2119, Intense Beams and Applications: Lasers, Ions, and Microwaves; (1994) https://doi.org/10.1117/12.172704
Event: OE/LASE '94, 1994, Los Angeles, CA, United States

Abstract

Kinetic modeling of the reactions that occur when molecular fluorine is mixed with the perfluoroalkyl iodides, RI, where R is methyl, ethyl, or n-propyl has been performed. The model that is utilized indicates that complex formation occurs initially in an extensive series of radical chain reactions. Wall reactions are incorporated into the kinetic mechanism and account in large measure for the formation of perfluoroethane during the reaction with the methyl homolog.

Citation Download Citation

Ernest A. Dorko, E. A. Walters, and Daniel E. Johnson "Kinetic modeling of the reactions between F₂ and the perfluoroalkyl iodides", Proc. SPIE 2119, Intense Beams and Applications: Lasers, Ions, and Microwaves, (1 June 1994); https://doi.org/10.1117/12.172704

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