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15 May 1994 Progress on heteroaromatic chromophores in high-temperature polymers for electro-optic applications
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Abstract
We have developed several classes of thermally stable nonlinear optical chromophores based on the combination of efficient thiophene conjugating units and novel electron-donating and electron-accepting functional groups. The incorporation of these chromophores into high temperature polymers produces high linear electro-optic coefficients and long-term thermal stability at elevated temperatures. Active Mach-Zehnder interferometers with a V(pi) phase shift of 50 volts and low attenuation (< 2 dB/cm) were fabricated. Thermal baking of the poled device demonstrated no change in activity after 30 minutes at 230 degree(s)C.
© (1994) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Alex K.Y. Jen, Varanasi Pushkara Rao, K. J. Drost, Yongming Cai, Robert M. Mininni, John T. Kenney, Edward S. Binkley, Larry Raymond Dalton, and Seth R. Marder "Progress on heteroaromatic chromophores in high-temperature polymers for electro-optic applications", Proc. SPIE 2143, Organic, Metallo-Organic, and Polymeric Materials for Nonlinear Optical Applications, (15 May 1994); https://doi.org/10.1117/12.173832
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