Rotational energy surface from the first principles

Sergei V. Petrov

doi:10.1117/12.166199

26 January 1994 Rotational energy surface from the first principles

Sergei V. Petrov

Proceedings Volume 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy; (1994) https://doi.org/10.1117/12.166199
Event: High Resolution Molecular Spectroscopy: 11th Symposium and School, 1993, Moscow, Russian Federation

Abstract

Detailed description of the cluster structure of rotational spectra based on the analysis of the Rotational Energy Surface (RES) was realized mainly by Harter and Patterson. This concept is very useful because the classical trajectories on RES are closely connected to quantum rotational spectrum. We wish to derive the quantum Hamiltonian from the RES constructed on the pure classical grounds. Here we limit ourselves with the consideration of the centrifugal interaction alone and isolated vibrational states.

Citation Download Citation

Sergei V. Petrov "Rotational energy surface from the first principles", Proc. SPIE 2205, 11th Symposium and School on High-Resolution Molecular Spectroscopy, (26 January 1994); https://doi.org/10.1117/12.166199

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available