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Impurities in mercuric iodide (HgI2) x-ray spectrometers are investigated by photoionization (PI) spectroscopy. The observed spectrum is shown to be a function of the particular impurities present in the material both in as-grown material and in material intentionally doped with Cu and Ag. The effect of contaminants on detector performance is also explicitly demonstrated as is the need for high purity starting materials and carefully controlled processing conditions.
John M. Van Scyoc III,T. S. Gilbert,Tuviah E. Schlesinger, andRalph B. James
"Photoionization investigation of defect traps in mercuric iodide room-temperature x-ray spectrometers", Proc. SPIE 2305, Gamma-Ray Detector Physics and Applications, (21 September 1994); https://doi.org/10.1117/12.187269
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John M. Van Scyoc III, T. S. Gilbert, Tuviah E. Schlesinger, Ralph B. James, "Photoionization investigation of defect traps in mercuric iodide room-temperature x-ray spectrometers," Proc. SPIE 2305, Gamma-Ray Detector Physics and Applications, (21 September 1994); https://doi.org/10.1117/12.187269