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30 September 1996Photochemistry of a three-component system usable in photopolymer plates
The excited state interactions occurring in a three- component system which can be used under visible laser light excitation and based on a derived dye thioxanthene derived dye TXD, an amine and an additive such as diphenyliodonium salt wee investigated through time-resolved absorption spectroscopy, spectrofluorometry and steady state photolysis. The rate constants of the various chemical processes taking place in the initiation step were measured. An overall photoinitiation mechanism is proposed. A sensitivity of 0.3 mJ cm-2 obtained under laser scanning exposition is also reported.
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Fabrice Morlet-Savary, Jean-Pierre Fouassier, Abdelali Erddalane, Y. Takimoto, "Photochemistry of a three-component system usable in photopolymer plates," Proc. SPIE 2851, Photopolymer Device Physics, Chemistry, and Applications III, (30 September 1996); https://doi.org/10.1117/12.251832