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The peculiarities of energy levels structure of laser-active F3+ color centers in LiF crystals were studied. The dependencies of polarization and fluorescence intensity of LiF crystals with F3+ centers against polarization of powerful laser irradiation which originates two-photon excitation of F3+ centers, were measured and calculated. It was shown that the two-photon transition leads to the excitation of unknown previously spin-singlet electronic state, possessing 1A1 wavefunction symmetry.
Tasoltan T. Basiev,Igor V. Ermakov, andKonstantin K. Pukhov
"Polarization investigations of two-photon excitation of F3+ color centers in LiF crystals and analysis of excited-state symmetry", Proc. SPIE 3176, Tunable Solid State Lasers, (1 November 1997); https://doi.org/10.1117/12.293441
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Tasoltan T. Basiev, Igor V. Ermakov, Konstantin K. Pukhov, "Polarization investigations of two-photon excitation of F3+ color centers in LiF crystals and analysis of excited-state symmetry," Proc. SPIE 3176, Tunable Solid State Lasers, (1 November 1997); https://doi.org/10.1117/12.293441