A mathematical model, based exclusively on spectroscopic data concerning radiative, non-radiative, and energy transfer processes, is proposed and used to simulate the Q-switch regime of three-micron Er:YAG laser. The connection between the main energy transfer mechanisms that make possible generation on the self-saturated transition ⁴I_11/2 yields ⁴I_13/2 (up- conversion from ⁴I_13/2 and ⁴I_11/2, cross- relaxation from ⁴S_3/2) and the giant pulse characteristics is discussed. The radiative as well as non- radiative losses during optical pumping and giant pulse generation are defined and evaluated. A particular attention is given to FTIR Q-switch which demonstrated real qualities for 3- micrometers Erbium lasers. The reasons responsible for experimental performances of Q-switched Er:YAG lasers inferior to those predicted by the mathematical modeling are analyzed.

The work addresses the problem of a CO₂ laser dynamics control in the presence of Gaussian white noise in the cavity losses. We improve the delayed continuous feedback method by introducing memory of the previous states. The method proves a powerful one that works for otherwise chaotic dynamics and regular dynamics equally well and it is robust with respect to noise.

The paper describes the methods used to adapt an industrial TEA- CO₂ laser to the requirements of the ISO standard 11 254-2 for a laser induced damage threshold experimental facility. The goals were to improve the pulse energy stability and the laser beam spatial profile and the methods were: (1) finding the best discharge voltage; (2) adapting the laser cavity, (3) using suitable apertures. There is also presented the experimental set- up for beam characterization, which included a laser beam profiler (a line of 60 pyroelectric detectors), an energy-meter to monitor the pulse energies and KCl optical components for beam splitting and beam guiding. Every beam distribution was regarded as a linear combination of normalized Gauss-Hermite functions and the fitting algorithm allows the calculation of the coefficients of this combination.

Based on the small gain approximation in the unsaturated regime in this paper we present the derivation and the evaluation of the spectral optical gain, spectral noise figure and spectral quality factor on single and double pass configuration Er³⁺-doped LiNbO₃ waveguide amplifier pumped near 1484 nm. The simulations show the evolution of the above mentioned parameters under various pumping regimes. In the present work we demonstrated that high gains and low noise figures are achievable in high pump regimes and double pass configuration. The obtained results can be used to theoretically model the optical amplification around 1500 nm in Er³⁺-doped LiNbO₃ waveguides are function of various parameters.

The output beam characteristics of a CW diode end-pumped miniature Nd:YVO₄ laser (1.1 at.%, 1 X 3 X 3 mm³) operating in fundamental and SHG regime are presented. Using M² factor to describe the multimode pump beam's propagation from the broad-emission-area diode-laser the coupling optics was designed to obtain a high value for the mode-matching efficiency. A maximum slope efficiency of (eta) _s equals 58.6%, with (eta) ₀ equals 53.8% optically efficiency at maximum pump power, characterized a laser resonator of 50 mm length in transversal TEM₀₀ mode. In the SHG experiments using a KTP crystal a maximum power of 100 mW was reach in a circular laser beam of 4.2 mrad half-angle divergence.

Within the framework of x-ray laser research using the recombination of heliumlike ions with free electrons to produce lithiumlike ions in expanding and cooling hot plasmas, we present a set of spectroscopic data required to improve the gain modeling. We estimate the cross section and rate for ion-impact excitation in aluminum Li-like lasing medium using the two-state approximation for transitions caused by a multipole interaction. The approximation used for atomic data calculation is presented.

We report Q-switching of a Nd:YAG laser with a phase-conjugating mirror based on external stimulated Brillouin scattering in carbon disulfide using a linear resonator. Q-switching is provided by a nonlinear LiF:F₂^- crystal before the stimulated Brillouin scattering takes place. Employing proper mode selectors pulses with 6 mJ minimum energy and duration of 20 ns were generated, the beam divergence being 1.5 the diffraction limit. A new theoretical model of the Q-switching regime has been proposed and good agreement between experimental and theoretical data has been obtained.

The features of a new upconversion mechanism of excitation, the sensitized photon avalanche, are discussed on the basis of a rate equation modeling. In this process the excited state absorption (ESA) from a metastable level (reservoir) of the active ion is enhanced by a cross-relaxation between the emitting level of this ion and the sensitizer ion which is able to transfer subsequently the accepted excitation back into the reservoir level of the activator; the donor act of the cross-relaxation ends on this reservoir level too. When the efficiencies of these two energy transfer processes are larger than specific threshold values related to the intrinsic de-excitation rates of the emitting level of activator and of the excited level of sensitizer, a process of population of the reservoir level with a quantum efficiency larger than the unit for each act of de-excitation of the emitting level takes place. Further on, if the ESA rate exceeds a threshold value determined by the intrinsic de- excitation of the reservoir and by the efficiencies of the energy transfers an avalanche population of these levels could take place. This process could be used for infrared pumping of visible solid state lasers. The theory is illustrated for Yb³⁺- sensitized visible emission of Pr³⁺ under infrared pump (835 nm).

Power stabilized DL's represent today convenient sources for radiometric applications, as transfer laboratory standards. Stability measurements were carried out and reported by other authors for different time intervals, but only for low optical power levels (max. 16 mW). For calibrating usual optical radiometers, such low emitted power DL's are useless. This paper reports stability measurements carried out on several collimated DL's with (lambda) around 980 nm and emitted power up to 265 mW in near-field/150 mW in far-field. Stabilities of the order 1e-4 for short-time intervals (tens of seconds) and 1e-3 for medium-time intervals (1 hour) were found for a non-thermostated structure, having the control photodiode (PD) in the same enclosure with the DL (at the rear of the structure). The corresponding stabilities for an external control PD resulted of the order 1e-5 for both short and medium time intervals. The schematic of the optical power stabilizer is presented.

A simple and inexpensive method to perform high resolution spectral studies of the green-yellow pulse shapes of a CuBr laser is presented. The radio-frequency (RF) spectrum of the temporal shape of the detected signal is called `pulse-shape spectrum (PSS). The individual 510.6 nm (green) and 578.2 nm (yellow) PSS are studied in the range 20 - 500 MHz with 1 MHz resolution. The RF spectral analyses of the compound signal (the weighted sum of the two pulses, one of them being delayed with respect to the other one) reveals that the coherence properties of the spectral components are dependent both on the pulsed mode excitation and the optical modes supported by the optical cavity.

In order to describe the transversal mode construction in a real laser resonator, a mathematical model was investigated. The analysis use Kirchhoff-Fresnel diffraction equation and amplification processes in the active medium, that was supposed as sum of thin discs with gain and losses constants on every disc's length. Influence of additional phenomenon on laser beam characteristics, as phase-shift caused by active medium thermal induced refractive power and curvature of the resonator mirrors were considered.

High power pulsed laser diodes are of interest due to their potential use in medicine and peculiar applications. This paper presents failure analysis for catastrophic damage in GaAs/AlGaAs LOC pulsed laser devices. There is presented failure decrease of optical power as 1 g (P/P₀) equals f(t) where P₀ is initial power, P actual power, t-operating time. The damaged devices were investigated by optical and scanning electron microscopy and there was performed a electron dispersion spectroscopy analysis. These experiments advanced the idea of dividing catastrophic degradation in three types, respectively: 1-catastrophic optical mirror damage, 2-catastrophic damage due to major mechanic defects, 3-catastrophic damage due to metal migration (e.g. Au). There was established an experimental criterion to characterize catastrophic damage.

We have developed a laser-diode pump system for continuous-wave end-pumping of Nd:YAG lasers. The pump system includes a pair of 1 W diode-arrays mounted in coaxial enclosures, a driver unit and the pump optics. The array wavelength was temperature tuned to achieve the maximum absorption of the pump radiation in the Nd:YAG crystal. The characteristics of the pump system are presented and the pump-beam profile is investigated.

We have developed a simple, all Pyrex, 60 cm active length laser tube in a self-heating geometry. For a He pressure of 20 Torr and a current of 120 mA, the laser power was 28 mW on seven lines in the blue-green region. By spectroscopic measurements we have determined the influence of metal vapor presence on the intensity of a helium line. Some modifications of the vapor clouds generated by a magnetic field are reported.

The paper discusses the effect of pump intensity variations caused by absorption in a fiber system with upconversion avalanche fluorescence or laser emission. The numerical modeling shows that in given pump conditions the initial part of the fiber (up to a distance z_th) is pumped above the avalanche threshold while the remaining part lies below it. This induces a strong variation of populations of the excited levels along the fiber. The characteristics of the avalanche emission are connected to the spectroscopic parameters of the system and to the conditions of pump. It is also shown that the features of the global luminescence emission at the end of fiber depend strongly on the fiber length for the short fibers (L <EQ z_th) but for the long ones this dependence diminishes; thus the avalanche emission of a long fiber could be different from that predicted by a constant rate modeling. The effect of distribution of local pump intensities on laser emission in avalanche-driven upconversion fiber lasers is also discussed.

A new optical resonator configuration for transverse flow CO₂ laser was developed. A high value of the matching coefficient (the cross section of the laser beam/the cross section of the electrical discharge)-(eta) _m, is obtained for laser beams with TEM_00/01 intensity distribution (that corresponds to the low values of the Fresnel number-N_F of the optical resonator). Simultaneously, both types of the gain and refractive index asymmetries of the active medium (parallel and perpendicular on the flow direction) are compensated. A 90 degree(s) deflection device is the main constructive element (this is built by two mirrors at 45 degree(s) relative angle and offers the pentaprism properties). This deflection device reverses the wavefront in one of the two discharge channel and in addition improved the resonator stability. The main results are (eta) _m is congruent to 0.83 for N_F is congruent to 1.9 and the beam pattern is independent of the power level in the range of 300 W to 1800 W.

An extensive comparison between two modeling methods: Method of Lines and Time Domain Method in analyzing the large signal responses of Fabry-Perot semiconductor lasers is presented. The methods are implemented in two numerical codes written in FORTRAN and using DIGITAL ALPHA workstations under VAX/VMS and UNIX operating systems. The comparison shows good agreement between the simulation results under specific conditions. A special accent is placed on the advantages and drawbacks of both methods by taking into account their numerical problems and the computational effort implied by simulations.

A generalized model of the cw three-micron emission in concentrated Er systems, which takes into account the whole variety of de-excitation processes is presented. The analytical equation for the flux of light enables a direct correlation of the parameters of emission (threshold, slope efficiency) with the spectroscopic parameters and pump conditions. The effect of excited state absorption is, also, put in evidence.

Carbides and nitrides of metal have a large number of applications in modern technology owing to their interesting, and in some ways unique, physical and chemical properties. Thin film coatings of titanium carbide and aluminum nitride were deposited on Si (100) substrates using pulsed laser deposition method. The structural and microstructural properties of these films have been characterized using x-ray diffraction, and Fourier transform infrared spectroscopic techniques. The mechanical properties of the films were evaluated to measure the hardness and modulus values. It has been shown that the films deposited at higher temperature have the best crystalline quality structure and also have higher hardness values compared to the film deposited at lower temperatures.

The effects of laser fluence on the structure and properties of the reactive pulsed laser deposited carbon nitride (CNx) thin films prepared at different gas pressures of N₂ and NH₃ were investigated. The structure, the morphology and the chemical composition of the films were characterized by X-ray photoelectron spectroscopy, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Rutherford backscattering and Fourier transform infrared. The films were plane, adhesive and relatively hard, with a low droplet density. The deposition rate decreases with increasing gas pressure and laser fluence, while the N/C atomic ratio increases. The nitrogen concentration in the deposited films drops when the substrate temperature is increased, indicating a desorption process of the CN radicals. Spectroscopic studies of the plasma plume indicates an interesting correlation between the CN band emission intensity and the nitrogen concentration in the samples.

Combustion diagnostics by means of 2D Laser Induced Fluorescence (2D-LIF) is applied to a diamond depositing oxyacetylene flame. The method and results of diamond growth are discussed, as well as the 2D-LIF technique. The distributions of atomic hydrogen, CN, and C₂ in the flame are presented together with their relations to diamond growth.

Nanosize powders of AlN was successfully synthesized by pulsed laser ablation. The target can be either Al or AlN, with ambient gas nitrogen. With Al targets, typical powder diameters were in the range of 2.5 divided by 25 nm. In order to study the process of powder formation, we have used a high-speed camera and a time-resolved spectrum analyzing system to investigate the behavior of the ablation plasma and the ion species in the plasma. For the diagnostic experiments, the target was Al and the ambient gas was oxygen.

A picosecond excimer laser-plasma source has been constructed which generates an x-ray average power of 2.2 Watt and 1.4 Watt at the wavelengths required for proximity x-ray lithography: 1.4 nm (steel target) and 1 nm (copper target), respectively. The plasma source could be scaled to the 50 - 75 W x-ray average power required for industrial lithographic production by scaling the total average power of the commercial excimer laser system up to 1 kW. The 1 nm x-ray source is used to micromachine a 2.5 THz microwave waveguide-cavity package with a 48 micrometers deep, 3D structure, using the LIGA technique.

The study of producing metal based oxides has become increasingly interesting because of several specific features which make them extremely attractive for various uses, e.g.: catalysts, pigments, magnetic records, sensors, etc. In the present paper we report the synthesis of various iron, copper and nickel oxides by the IR laser processing of different salts. X ray diffraction technique was used in order to characterize the reaction problems. An analysis of the differences between these oxides and those obtained from the same salt by thermal means is presented. It was found that the oxides obtained by laser processing show specific characters concerning the crystallinity and chemical composition.

We report the synthesis and deposition of TiC films by reactive pulsed laser deposition. Ti targets have been submitted to multipulse UV laser action in low pressure CH₄. The thin films were grown on a collector placed parallel to the target. The films were characterized by electron microscopy, electron spectroscopy and nuclear techniques.

Ultrafine alumina powder was produced by aluminum target ablation with a Nd:YAG laser beam (1064 nm wavelength; 340 mJ/pulse energy; 7 ns pulse duration; 10 pps repetition rate), in a 120 Torr O₂ atmosphere. A theoretical approach for the ablation process, based on laser energy absorption and energy balance in the target, is used for comparison with the experimental production rate. Three experimental irradiation conditions were chosen: (1) energy density of 5 J/cm², considered reference (RDE), (2) lower energy density of 2.5 J/cm² (LDE) and (3) RDE with auxiliary discharge between an auxiliary electrode and target, triggered by the ablation plume (RDA). Calculated and experimental data of target weight loss show good agreement (135 ng/pulse, calculated, and 100, 110, 120 ng/pulse, experimentally, for RDE, LDE, RDA conditions, respectively). The X-Ray Diffraction spectra of alumina show formation of (gamma) -alumina particles only, especially in LDE and RDA conditions. From Scanning Electron Microscopy size analysis, a decrease of particle size, in LDE and RDA irradiating conditions, is observed. The decrease of laser beam fluence or aiding of ablation using an auxiliary discharge is both favorable for the production of high quality powder, without diminishing the production rate. This can be a good basis for future improvement of the ultrafine powder production process.

Since the theoretical studies of Liu and Cohen who predicted the existence of a superhard phase of carbon nitride, a great deal of effort was underdone in order to synthesize this hypothetical material with a nitrogen content as high as the 57% present in a (beta) -C₃N₄ structure. This study presents an attempt to produce CN_x thin films using the laser-induced CVD technique. CW CO₂ laser was used for irradiating various carbon-nitrogen containing mixtures such as C₂H₄/N₂O/NH₃. The CN_x films were grown alternatively on bare alumina ((alpha) - Al₂O₃) substrates and on pre-deposited Ti films. A comparative analysis of nitrogen incorporation in the films obtained in different experimental conditions was performed by means of the X-ray photoelectron spectroscopy. The same method was used to identify the chemical states of the CN system.

The influence of the thermal annealing on the optical properties of the porous silicon films was revealed by photoluminescence (PL) and spectroellipsometric measurements. As result of 200 degree(s)C annealing small changes of the dielectric functions could be understood by desorption process of some molecules from Si skeleton surface. Strong changes of PL and dielectric function spectra after the thermal annealing at high temperatures (up to 800 degree(s)C) were explained by the change of the passivation from hydrogen to oxygen and then the beginning of the oxidation process. This oxidation process produces the disappearance of the PL slow component, an important enhancement of PL (2-3 orders of magnitude) and a shift of maximum position to higher energies, corresponding to the thinning of the nanocrystallites from the Si skeleton.

Some inexpensive optical devices using small silica-gel spheres are presented. The silica-gel spheres of good quality are investigated under the microscope. These sphere presents some particularities which make them very useful in applications like interferometry, hygrometry and optical microscopy. Such small spheres may be doped with microcrystals or dye solution in order to study a large range of nonlinear phenomena. Experimental studies have been performed on the silica spheres as alternative media for laser action using a pulsed CuBr laser as excitation source.

Hydroxyapatite (HA), Ca₁₀(PO₄)₆(OH)₂, is the primary constituent of the human bone and one of the best biocompatible materials. In this work we developed a simple method for the deposition of polycrystalline HA thin films onto various collectors including substrates of medical interest (e.g. Ti). We proceeded by the pulsed laser deposition of HA targets onto parallel collectors placed at (2-5) cm in vacuum. After deposition the films were heated in air at 500 degree(s)C for 30 minutes. The heated film has a structure which appears in electron diffraction as identical to the structure of the base material. The obtained films are uniform and very adherent to the substrate. The P/Ca atomic ratio, determined by energy dispersive X-ray analysis, was found to be close to that characteristic to HA, for the post-depositing heated films.

The role of the sub-surface explosive boiling mechanism for droplet formation during the pulsed laser deposition of thin films has been examined. For photons with an energy lower than the target optical band-gap, hv<E_g, a highly perturbed target surface morphology exhibiting micrometer sized round- shaped cavities always formed, whereas for hv>E_g the surface was much less perturbed. Depth-profile estimations of the temperature profiles inside the laser irradiated targets were also quite different for these two cases. For low optical absorption coefficient (OAC) values, (alpha) < 5 X 10⁴ cm^-1, a thick layer of liquid formed whose maximum temperature was located at some point below the surface. Simultaneous to the cavity formation, the droplet density on the surface of the grown films was found to increase by orders of magnitude, indicating a clear connection between the target OAC, the temperature profile, the presence of the cavities and a high droplet density. The decrease of the OAC value during prolonged laser ablation could also explain the gradual increase of the droplet density observed when growing La_0.5Sr_0.5CoO₃ films. Based on these results, we suggest that an important fraction of the droplets on the surface of films grown under laser irradiation conditions where the OAC is smaller than 5 X 10⁴ cm^-1 is caused by an explosive sub-surface boiling mechanism.

Obtaining sharp and sometimes special patterns on hard materials surfaces (texturing) is rather difficult by conventional procedures, which made the laser an attractive choice in this matter. Absorption of Nd:YAG's 1.06 micrometers radiation in most steels and ceramics, which are the common materials for textured surfaces, is good such that average power lasers can be used. In this paper we are concerned with the principal phenomena involved in the texturing process and with the sought of a simple mathematical model that will allow to choose right working regime, and make estimations about the system performances (speed, power consumption, etc.). Experimental data were obtained by using both a Electro-Optically Q-switched CW laser with an average power of up to 100 W and a pulsed free running laser with an average power of up to 100 W and pulse energy of up to 10 J. The experimental set-up includes an X-Y stage and two gold deflectors used to cover the entire surface.

The compound Mercuric Bromoiodide (HgBr_xI_2-x) belongs to the HgI₂-HgBr₂ system. It is promising for the same applications as HgI₂, that is as solid state X and (gamma) detector, operating at room temperature since it exhibits a number of properties which are necessary for such applications, i.e. large atomic number, large band gap (2.4 - 3.4 eV) and high resistivity. Using a Confocal Laser Scanning Microscope we made some investigations regarding topographical distribution of impurities or related defects. Analysis of chemical composition of HgBr_xI_2-x crystals were performed on a SEM model Phillips 515 equipped with Energy Dispersive X-ray Analysis.

The selection of the best laser for a given application is a common problem of laser users. However, a direct relationship between laser intrinsic characteristics and a potential application, risks to make the laser source selection process unilateral and partially mistaken. In fact, the best processing technology for a given application must be chosen. Therefore, the present paper proposes an indirect, more realistic selection process. This process starts from a general laser application definition. Then, it passes through the analysis of the needed laser beam--workpiece material interaction and of the necessary laser technological system. Finally, the selection process ends with the laser processing technology definition, where the choice of the most suitable laser source becomes in fact possible.

NiO is a metal-deficient p-type semiconductor with surface defects which are correlated with the non-stoichiometry. The dissociative H₂ adsorption on the NiO surface takes place on oxygen-excess sites (over equilibrium). The H₂ TPD spectra vary significantly with calcination temperature (stoichiometry) and chemical treatment UV laser radiation enhances H₂ adsorption on the defective surfaces (non-stoichiometric) as compared with the stoichiometric ones, even chemically treated. The fourth harmonic of a Q-switched Nd:YAG laser is used for the NiO samples irradiation. The wavelength of the UV laser radiation is 266 nm, under the band-gap of the semiconductor.

In this communication we present the results of computational modeling of molecular units as As_mS_n registered by mass spectrometry in the As₂S₃:Sn_x glasses before and after laser illumination. Using HyperChem Computational Chemistry program we obtained 3D structures, with global minimum energy conformation for following molecules: As₄ (3.47); S₈ (4.44); As₄S₃ (11.87); As₂S₅ (14.36); As₂S₄ (17.62); As₂S₆ (19.11); As₄S₄ (21.88); As₄S₅ (24.98); As₂S₃ (25.81); As₄S₆ (43.13). The model of the As₂S₃:Sn_0.1 glasses, using 200 As atoms, 300 S atoms and 10 Sn atoms for computational modeling, is presented too. Such model shows that a tin atom may be bonded in two ways: when the tin atoms are common for two rings with 12 atoms and when the tin atom are bonded between the layer of the glassy network. When the tin atom are insert in the network rings for 12 atoms the structural model shows the more compact packing of the atoms.

Arrhenius plots and current-voltage characteristics were studied for natural quartz samples, in different conditions of air- sweeping time, of temperature, of electrodes (with or without any source of positive ions). Some observations about the influence of the ionic space charge limited current are made. Some dependencies of ionic current versus voltage were found.

The processes involved in the melting and solidification of powders have been studied, in order to obtain 3D pieces. The experiments have been performed with a CW Nd:YAG laser, but the Q-switched regime has been also used. Measurements about compacting rate for different parameters (scanning speed, thickness of layer) and a comparison between the two regimes have been made.

Thin films of hydroxyapatite (HAp) have been grown on Si, quartz, Ti, and Ge substrates by the pulsed laser deposition (PLD) method employing a KrF excimer laser (wavelength (lambda) equals 248 nm, pulsed duration (tau) _FWHM equals 20 ns). The influence of the laser deposition parameters on the properties of the grown layers was investigated in order to optimize the Ca/P ratio and the crystalline structure. It was found that the optimum conditions for preserving the Ca/P ratio i.e. high oxygen pressures and low substrate temperatures do not coincide with those for obtaining adherent and crystalline layers i.e. low oxygen pressures and high substrate temperatures. For films deposited onto Ti substrates it was also found that high substrate temperatures promote the diffusion of Ti through the depositing film up to the surface where it gets oxidized. Further investigations are required before high quality HAp-coated Ti implants by PLD can be obtained.

A numerical method for simulating realistic problems of mode coupling in optical transmission systems is described. The conclusion concerning waveguided propagation of the electromagnetic field in complex structures, selective mode excitation and the power transfer may become an important factor in designing and connecting devices used in optical signal processing. The numerical method is based on an extension of the `Orthogonal Collocation Method' to the case of coupled systems of differential equations with an infinite range of independent variables.

Fast-framing photography was used to study the effect of various parameters on the expansion of the visible plasma plume produced by KrF laser irradiation of a YBa₂Cu₃O_7-x target. The ambient gas pressure has a considerable effect on the evolution and structure of the plasma. In vacuum, the visible emission is strongly forward-directed and has a relatively short duration. In the presence of an oxygen atmosphere, a long-lived, highly luminous front is formed, whose expansion may be well described by a drag model or a shock model (spherical or plane shock). Ahead of the luminous front there is weak emission, which for pressures over about 700 mTorr evolves into a highly emissive `tip'. The decrease of energy density on the target by increase of the laser spot (defocusing) leads to a more forward-directed motion of the visible species. Larger energy densities obtained by increasing the energy/pulse lead to a sharper, `V' shaped front. The effect of a biased ring electrode placed 0.5 cm to 2 cm in front of the target was also studied. The emission characteristics in the electrode's presence change greatly. The effect of ring-target distance, voltage magnitude and polarity, and pressure were observed.

The purpose of this study is to establish the way in which different synthesis conditions influence on the structural and luminescent characteristics of europium activated calcium tungstate powder phosphor. CaWO₄:Eu³⁺ samples were prepared by thermal synthesis from mixtures consisting of precipitated-CaWO₄, equivalent amounts of Eu₂O₃ and WO₃ (activating system) and CaCl₂ or Na₂WO₄ as flux. Calcination was performed at 800 - 1000 degree(s)C for 2 h, in air. The crystalline structure (XRD-patterns) and luminescent characteristics (emission and excitation spectra of phosphor samples were determined and interpreted.

From the phenomenological point of view, laser cutting processes are complex, weakly organized and diffuse systems. Off line optimization of such processes demands relative simple, but accurate enough models, which could be obtained by experimental way. The article presents the results of a large factorial designed experiment, having three main objectives: to identify which factors are statistically important, to build a quantitative model relating the important factors to the response functions, to optimize these response functions and particularly the material removal rate, the kerf walls parallelism deviation and the specific energy consumption. The obtained results allow the choice of laser cutting optimal parameters.

The aim of the paper is to optimize the microholes machining, in the case of laser drilling. The laser used for experiments was a Neodim-15 laser. The material used for drilling was 41MoCr11 austenitic stainless steel with a 1,5 mm thickness. As parameters of the laser drilling process were considered: diaphragm diameter, focal point position, focal length of the lens and laser pulse power. The objective functions were the diameter of the microhole in the area of the laser beam entrance of material (Di), the diameter of the microhole in the area where the laser beam exit the material (De), respective their tolerances (Ti and Te). It was used on complete factorial experiment 2⁴. The established mathematical models are useful in finding the optimum values of the parameters in various combinations, such as the hole diameter to be closer to the required diameter.

We introduce a theoretical model to describe all the phenomena implied in the interaction process between the high intensity UV laser radiation and a solid target in the ambience of a low- pressure chemically active gas. The action of the laser radiation upon the solid surface is simulated by solving the 1D heat equation. A hydrodynamical 1D model was further applied to describe the interaction between the laser radiation and the plasma expanding in front of the target. The absorption of the laser radiation in the vapor plasma could be considered with the aid of a multifluid model. The transit of the ablated atoms and/or of the new formed chemical compound was approached with a Monte-Carlo method. We could compute time and space distribution of the main plasma parameters (e.g. the plasma density and temperature). We could finally predict the thickness distribution of a film deposited on a collector placed parallel to the target at a distance of (1.5 - 3) cm range. The calculus was conducted for the case of a Ti target in low pressure nitrogen.

A comparatively study of pulsed-laser and alpha particle irradiation effects in metallic glasses has been performed in order to understand the relationship between magnetic behavior and select variations in the structural characteristics of alloy phases. Samples of Fe₇₈B₁₃Si₉ and Fe₆₆Co₁₈B₁₅Si metallic glasses were irradiated with a pulsed excimer laser ((lambda) equals 308 nm, (tau) equals 10 ns) and alpha particle beams (W equals 2.8 MeV) using radiation doses of 10¹⁶ and 10¹⁷ cm^-2. Irradiation-driven changes in the magnetic anisotropy and phase equilibrium of alloy samples were studied by Mossbauer Spectroscopy and scanning electron microscopy. The evolution of phases and microstructure during the radiation- induced amorphous-to-crystalline transformations or revitrification depend on the specific irradiation and sample composition.

In this paper recent experiments performed in our laboratory are reviewed dealing with the investigation of quantum phenomena in the radiation interaction of single atoms. The first part describes experiments in single mode cavities using the one-atom maser or micromaser and in the second part experiments with ion traps are summarized. The latter experiments concentrate on the investigation of resonance fluorescence. In addition new experimental proposals using ultracold atoms in cavities and traps are discussed. In those future experiments the interplay between atomic waves and light waves is important and leads to new phenomena in radiation-atom interaction.

The optical properties of layered materials of a fractal quasiperiodic structure are reviewed considering both the case of wavelength smaller than the thickness of the thinner layer and the reverse case in which the whole structure is much smaller than the wavelength.

We apply the quasiadiabatic approximation for the femtosecond pulse propagation in a collection of excitons in the case of weak interaction between the optical pulse and the semiconductor medium. Using the semiconductor Maxwell-Bloch equations beyond the slowly varying envelope approximation we show that the dynamics of femtosecond pulse propagation is described by the modified Korteweg-de Vries equation. Bright solitons superimposed on a continuous wave background are found and their stability against low amplitude perturbations is investigated. Possible experiments in semiconductor systems such as GaAs/AlGaAs are discussed.

The wavelet transform is a very common and useful tool for image processing and compression, however, it requires heavy computations. Optics is useful for rapid computation of parallel information channels. In this paper various important approaches for the optical implementation of 2D wavelet transform as well as the optical wavelet processor are presented and discussed.

In this paper, the density of modes in quantum cubic cavities is calculated taking into account the small number of modes. Then the `spatial quantization' fluctuations, which appear as a correction factor in the mode density, are introduced in the Planck law. The discrete form of the Planck radiation spectrum is demonstrated and the limits of this double-quantum regime of the cubic cavity are set for the product of cavity size by temperature. LT(epsilon) (0.1, 1). A reciprocity rule for the cavity size and the temperature is shown. Calculating the total energy in the quantum cubic cavities (QCC), we found out a `corrected' Stefan-Boltzmann law for the double-quantum regime. Furthermore, the corrections for all thermodynamic functions of the photon gas in QCC are given.

The interaction of radiation with vitreous materials provokes irreversible and reversible changes of atomic and electronic structures. These changes in their turn manifest themselves in the experiment through changes of mechanical, thermal, optical, photoelectrical and other characteristics. Under the radiation influence the structure of vitreous materials changes, new defects appears, film crystallization or amorphization takes place, phase transition or transition from one unstable state to another. It is evident that such changes radically influence the optical and photoelectrical properties of the material: the refraction index and other optical material constants change; reflection and absorption of light as well as photoelectric parameters. Of no less importance is the appearance of new possibilities for application of vitreous materials as optical and photoelectrical recording media, fibers and planar waveguides, active and passive elements of optoelectronics, including nonlinear elements and sensors of different physical quantities. This paper covers a survey of works dedicated to the research of various photoinduced phenomena in bulk, thin-film and fiber samples of chalcogenide glassy semiconductors.

The thermooptic constants of AgGaSe₂ have been measured at 2.052, 3.3913, 5.2955, and 10.5910 micrometers . These results combined with the literature values were used to construct the thermooptic dispersion formula which correctly reproduces the temperature dependent phase-matching conditions for second-harmonic generation and sum-frequency generation of a CO₂ laser as well as the thermally induced lensing effects for the 2.05 micrometers pumped parametric oscillators.

We analyze the two-photon cooperative emission of excited atoms in microcavities with dimensions of the order of the emission wavelength. Here the two-photon dipole-forbidden transitions between the upper and the ground states of the three-level system are possible through the intermediate level that is off resonance with microcavity modes. In this situation one obtains the powerful pulse of two-photon highly correlated light. The superbunching phenomenon in radiated field is also discussed.

The hysteretical behavior of imaginary and real parts of the semiconductor susceptibility in the exciton range of spectrum taking into account the exciton-photon and elastic exciton- exciton interaction in the pump-probe regime depending on the intensity and frequency of the strong pump laser pulse and on the frequency of the test pulse is studied. The conditions of the emergence of the damping suppression and test pulse gain are determined. The abrupt red and blue shifts of the spectral position of the exciton absorption band depending on the intensity of the pump pulse are predicted.

The theory of regular and chaotic self-pulsations in a CuCl crystal with the participation of coherent excitons and biexcitons is elaborated. The method of chaotic self-pulsation suppression in the system of coherent excitons and biexcitons is proposed. This method consists in action of external periodical turbulence upon a stochastic system. The range of amplitude values and frequencies of external harmonic pump were found at which the chaotic oscillation regime becomes nonlinear periodic by transformation of strange attractor into a limit cycle. The feasibility of observing the predicted effects in experiment is discussed.

Morphological correlation is a novel method for obtaining high discrimination ability in pattern recognition applications. It provides also important abilities for image compression and image analysis. The concept is based on slicing the input image and the reference filter into many binary slices, e.g. 255, and correlating them. The morphological correlation is defined as the summation of these correlations. The morphological correlation is characterized by a sharp correlation peak narrower than that exhibited by matched filter. The disadvantages are the requirements of performing many correlations and its very high sensitivity to noise added to the reference image. In this presentation we suggest two methods to solve both drawbacks. First, instead of 255 correlations we suggest to utilize only 8, by representing the grey level of each pixel by its 8 bit binary representation. Then, 8 binary masks are constructed according to the binary representation. In order to address the problem of severe sensitivity to noise, we suggest to sum the 255 correlations of the morphology slices while each slice is multiplied by a weighting factor which equals the correlation peak of that specific slice with noise divided by its correlation peak value when no noise is added. The solutions suggested here were examined by computer simulations demonstrating considerable improvements in the performance of the morphological correlator.

The use of circular harmonics to design correlation filters represents one of the most powerful approach in one-target recognition with in-plane rotation invariance. Recognition of more than one target can be achieved, on the other hand, using synthetic discriminant functions. In this paper we describe how can be combined these two techniques to design a filter which ensures rotation invariant recognition of multiple targets in parallel. The usefulness of the filter is demonstrated, for the case of two targets, by experimental results obtained from computer simulations.

Light-induced charge gratings at the surface of a photorefractive Bi₁₂SiO₂₀ crystal are investigated using electrostatic force detection with an atomic force microscope. The gratings with periods of 2.7 micrometers and 0.22 micrometers are generated by two intersecting Ar⁺-laser beams at 514 nm. The dark decay times of the stored gratings are determined. Saturation processes are directly observed by a change of the profile of the charge gratings. The polarity of the charge carriers in the material is obtained using a simultaneous measurement of the light-intensity grating.

The bistability that we are describing results from designing properly the cavity of a Distributed Bragg Reflector laser realized with an external fiber grating and is based on longitudinal mode competition. The analysis of the output power bistability is done with a simulation of the static behavior of the laser. An accurate and fast computing algorithm has been implemented to solve the steady state rate equations for photon and carrier density. The used model is based on multimode analysis and includes gain saturation.

The paper summarizes the peculiarities of the nonlinear interaction of short laser pulses with the noncrystalline semiconductors (chalcogenide glasses, a-Si:H), showing that noncrystalline semiconductors (NS) are an interesting material for high speed optoelectronics. The physical mechanisms, which can contribute to the nonlinear light absorption in NS under pulsed excitation, are reviewed.

We describe a pulsed doubly resonant LiB₃O₅ (LBO) optical parametric oscillator (OPO) pumped with a frequency doubled Q- switched Nd:YAG laser amplifier. The threshold power density near degeneracy was found to be 29 MW/cm². The OPO was continuously tuned from 970 nm to 1175 nm by rotation of the LBO crystal. The linewidth of the signal radiation at 998 nm, and idler radiation at 1136 nm wavelength, were found to be 10 nm, and 13 nm respectively. The OPO output pulse energy of signal and idler near degeneracy was 1.51 mJ for 18 mJ pump energy.

In this paper we report an indirect method based on photomultiplier response calibration to measure the radiant power of the internal second harmonic generation (ISHG) from InGaAs/GaAs/AlGaAs strained single quantum well buried heterostructure laser diodes. We observed enhanced ISHG radiant power, of the order of magnitude of 10^-8 W. This phenomenon represents a signature of the beginning of the process of catastrophic optical degradation of the LD mirror facet layers, where the nonlinear optical interaction occurs.

A theoretical investigation is reported of steady-state nonlinear transmission of resonant laser radiation by a thin semiconductor film under the conditions of two-pulse generation of excitons and biexcitons. The equations of state are derived for the description of bistable behavior of the amplitudes of the transmitted pulses and of the quasiparticle concentration, depending on the parameters of the exciting fields. The criteria of existence of an optical bistability are determined.

A study is reported of the influence of the saturation of the dipole momentum of an exciton transition on transient transmission of ultrashort laser pulses by a thin semiconductor film in the exciton range of spectrum. It is shown that when rectangular pulses of resonant laser radiation are incident on the film, a threshold-type qualitative change in the transmission by the film takes place from almost total reflection at low level of excitation to complete bleaching at high values of the incident pulse amplitude. An analog of the McCall-Hahn area theorem is derived for ultrashort pulses interacting with the film. When the nonlinear parameter is large, the dependence of the area of a pulse transmitted by the film on the area of an incident pulse becomes multivalued.

Several image encryption methods have been recently considered. This paper presents a new image enciphering method starting from the mixing transformations suggested by C.E. Shannon for natural language. There are two ways in which images are involved here: first, as a means of visual perception of the mixing transformation features (the very sophisticated diffusion and confusion); secondly, as the application field itself. Both the theoretical and experimental aspects pointed out here show the high quality of this method of image enciphering. The method illustrates were made either for simulated images with different probability laws and autocorrelation functions, or for natural images.

In this paper we report some experimental results concerning the characterization of the silicon guided-wave optical directional couplers and asymmetrical Mach-Zehnder interferometers from the transmitted spectrum in the 1480 - 1620 nm wavelength region. The experimental results were used for the evaluation of several parameters which define the above mentioned devices, like: the power coupling ratio, the perfect coupling length, the effective interaction length increment and the effective refractive indices, respectively. First, the experimental data were smoothed and fitted by a fourth order function in the case of waveguide directional couplers and a cosine type function in the case of asymmetrical Mach-Zehnder interferometers, respectively. Then, the evaluation of the above mentioned parameters was performed using the least-square method.

Interfacial turbulence is investigated experimentally by microscope observations and holographic interferometry with double exposure for the system glycerol-acetic acid-n-butyl- acetate. This system exhibits organized interfacial activity upon transfer of acetic acid from glycerol phase to acetate phase. This behavior was confirmed by the microscope observations in transmitted light. For the holograms obtained the deviation of the fringes between the two exposure times can be related with the changes in the concentration profiles near the interface. Because of the complexity of the phenomenon investigated, the present study is only qualitatively.

We performed both experimental and theoretical studies on the laser radiation absorption coefficient of a copper surface. A theoretical model for the computation of the absorption coefficient was elaborated for two-layer case (metal-oxide), taking into account the nonlinear processes which govern the dynamics of the temperature and of the widths of the layers. The experimental data and the simulation results proved to be in a very good agreement.

In this work we use a technique inspired by the inverse problem in the scattering theory, that is, the calculation of partial derivatives along the characteristic directions of the D'Alembert solution of the wave equation (Maxwell and Euler). In this way, we construct a system of stochastic non-linear differential equations. The analysis of this system, using algebraic invariants, gives more information in comparison with that given by Ghelfand-Levitan-Marcenko, in the inverse problem in the scattering theory.

In analyzing the polarization spectral structure of the time- varying spinorial fields obtained by light modulation, the notions of spectral Jones vector and spectral coherence matrix are introduced. The KDP longitudinal electrooptic modulator is presented as an example.

Conjugated wavefront fidelity has been evaluated using an interferometer with a phase conjugate mirror and fringe pattern computer processing. The quantitative interpretation of the fringe patterns is performed using direct spatial phase reconstruction methods (in the space and Fourier domain). A set of algorithms for fast and accurate phase evaluation, by fringe pattern processing, were derived. The result of optical interferograms evaluation appears in terms of different phase representations. These methods have been verified by studies of the optical phase conjugation fidelity in photorefractive crystals.

Improvements in Talbot-moire deflectometry are presented. A Talbot-moire interferometer, using a laser diode as light source, a single grating and a CCD camera, placed in one of the Talbot planes, was set-up. The computer yields a moire pattern by mixing the acquired Talbot image of the first grating with the reference generated by computer or stored as an undisturbed external grating Talbot image. For moire pattern processing, direct spatial reconstruction of optical phase, in spatial and Fourier domains, implemented in a high-level image processing language (IDL^TM), was employed. The theoretical limit of the relative error of Talbot-moire deflectometry was verified by measuring the focal length of a lenticular system with controlled-focal- length.

The paper presents a data processing algorithm, based on a deconvolution technique that enables the recovery of the low intensity spectral lines, in connection with the analysis of the radiative mechanisms from the non isothermal plasma of a hollow cathode discharge. This method represents a useful tool in the study of the radiative competitive processes involved in the selective excitation mechanisms for UV and visible spectral line's emission. It permits the evaluation of the second kind collision's weight in conjunction with the concentration of the plasma ions for different discharge parameters.

Light waveguides were obtained by ion-exchange process in soda- lime glasses. Metal nanoclusters were subsequently formed in waveguides by either low-mass ion irradiation, at energies of 20 - 2000 keV, or by heating in hydrogen atmosphere at temperatures varying in the range 100 - 250 degree(s)C. Nanoclusters modification induced by pulsed laser irradiation were investigated. The materials were characterized by secondary ion mass spectrometry and nuclear techniques, such as Rutherford backscattering spectrometry, to determine concentration depth-profiles, and by transmission electron microscopy for the nanoclusters detection and size evaluation. Optical analyses were performed to evidence linear and nonlinear properties.

We present a new scheme of sub-Doppler laser cooling for atoms used in atomic frequency standards, particularly for ⁴⁰Ca. We perform calculations concerning optical pumping via a velocity- selective state based upon velocity-selective coherent population trapping. Optical pumping on the Raman transition 4¹S₀- 4¹P₁-3¹D₂ leads to population of the metastable singlet state followed by a decay into the metastable triplet state 4P₁. The momentum distribution of atoms in that state (with a half-maximum width of about one corresponding photon recoil momentum) is a direct replica of the distribution of atoms in the 3D₂ state.

Analytic steady-state solutions of the density-matrix equation are discussed for multilevel spin systems in dilute paramagnetic solids at high temperature and subjected to three frequency- correlated fields at resonance. Unlike the double resonance, in the case of triple resonance, when the three microwave fields are sufficiently strong and the spectroscopic bridge conditions are satisfied, important linear and nonsaturating effects are predicted.

A CO laser has been used in combination with photoacoustic detection to monitor traces gases emitted from individual pieces of fruit under changing conditions. Ethanol and acetaldehyde have been detected as indicators of fermentation, ethylene for ripening and ethane for lipid peroxidation during deterioration of cell membranes.

The sensitization with Yb³⁺ of other rare earth ions emission is intensively used in the last years for increasing excitation efficiency of infrared (diode laser) pumped solid state lasers. It proved as a good sensitizer for Pr³⁺ emission in various matrices. The spectral investigations for the elucidation of the nature of multisite structure of Pr³⁺ in YAG and of the Yb³⁺ co-doping on Pr³⁺:YAG are presented in this paper. In Pr³⁺:YAG two types of multisites have been observed: perturbed Pr³⁺ sites by nonstoichiometric defects and strongly coupled Pr³⁺ - Pr³⁺ near neighbor pairs. Pr³⁺ spectra in Yb³⁺, Pr³⁺:YAG show new lines assigned to near neighbor Pr³⁺ - Yb³⁺ pairs and Pr³⁺ - Yb³⁺ - Yb³⁺ triads.

This paper presents a theoretical treatment of electron-phonon interaction problem in the case of quasi resonant interaction for rare earths ions in laser crystals. Expressions for the absorption or emission lineshapes (asymmetries or splittings of zero-phonon lines) are obtained. The theory is applied to explain some spectral features of Yb³⁺ transitions in YAG; it allows also the estimation of the vibronic coupling strengths, phonon energies and the `unsplit' electronic levels. A new electronic energy level scheme of Yb³⁺ in YAG is proposed.

Photoacoustic studies of the vapors of the essential oils of thyme, mint and anise have been made using a line-tunable waveguide CO₂ laser in conjunction with a heat-pipe type of photoacoustic vapor sample cell operated over the temperature range 20 - 180 degree(s)C. Identifying spectral fingerprint features are found in the 9 - 10 micrometers spectral region for each of the three essential oils investigated. The principal features of the photoacoustic spectrum of each essential oil are associated with the dominant chemicals present i.e. thymol in thyme oil, menthol in mint and anethole in anise.

We investigate theoretically a process of coherent Raman scattering in a medium where the coherence between two low- energetic levels is presented by adiabatic population transfer. In the present case the light induced moving optical grating can be formed by a periodical sequence of solitary-type waves (adiabatons). The parameters of this grating (propagation velocity, coefficients of spatial Fourier decomposition) are controlled completely by the amplitudes and phases of the two coupling fields at the medium entrance.

The effects of co-doping with Cr³⁺ on the absorption and emission characteristics of double doped Cr³⁺, Nd³⁺:YAG (yttrium aluminum garnet) are analyzed. The multisite structure due to co-doping (samples with a large range of Cr³⁺ content were used) is separated from that in single doped crystals. At least seven new lines have been separated in high resolution spectra and a tentative assignment in terms of structural data is proposed. These data suggest that the energy transfer data should be analyzed in terms of inhomogeneous system. However, the measurements indicate strong migration effects. The global donor and acceptor data at 300 K show a linear dependence on donor concentration, but the decays cannot be described in terms of published theoretical models.

Trichloroethylene with added molecular oxygen was photolyzed with a TEA CO₂ laser radiation, at v₄ (933 cm^-1) fundamental vibrational band for C₂HCl₃ and at v³ (1020 cm^-1) fundamental vibrational band for C₂DCl₃. The stable final products in the infrared multiphoton dissociation of trichloroethylene were determined by mass spectrometry in the 0.5 - 10 Torr pressure range of the gas. After the photodissociation process, the following final products appeared: HCl (or DCl), C₂Cl₂, C₂Cl₄, C₂Cl₄O, CO, Co₂ and C₂O₃. Experimental measurements were also performed to obtain information about the dependence of the specific dissociation rate versus laser pulse energy, for both isotopic species of trichloroethylene.

A study on the space distribution of the excited xenon atoms on level 1s₄ in a d.c. discharge in neon-xenon mixture is presented in this paper. The relative density of the excited xenon atoms was measured using diode laser absorption at 828.239 nm, corresponding to the xenon transition between 1s₄ and 2p₅ levels. A comparative analysis of the laser absorption signal and corresponding optogalvanic signal, permitted us to define a new parameter, namely optogalvanic effect efficiency, Eff_OG, as the size of the optogalvanic signal corresponding to an atom optically pumped by laser.

In this paper we discuss the heat produced by the non-radiative (multiphonon) transitions in Er:YAG laser rods, during the optical pumping, using the mathematical modeling. Three energy transfer processes (up-conversion from ⁴I_15/2, up- conversion from ⁴I_13/2, and cross-relaxation from ⁴S_3/2) are included in the rate equations. The main result of our simulation is that for usual optical pump conditions (Xenon flash-lamp, pumping pulse duration 200 - 300 microsecond(s) ) more than 50% of the absorbed energy is lost as heat in the active medium and only a small fraction (approximately 1%) is lost as fluorescent emission.

Some interesting experimental results involving new synthesized liquid crystals, derivatives of 4,4'-dihidroxyazobenzene and 4,4'-dihidroxy-azoxybenzene inferred by means of optical absorption spectroscopy are exposed. The absorption spectra dependence on the sample temperature in both heating and cooling processes is investigated. At the same time, the optical density is recorded at a fixed wavelength and it presents significant variations at phase transition temperatures. These data complete the results correlated with mesomorphism, obtained by classical techniques (DTA and microstructural analysis in polarized light).

The photoluminescence (PL) decay measurements were performed on porous silicon films. It was observed that the two components of PL, one of them fast (ns) and the other slow (microsecond(s) or ms sometimes) have different contributions to PL signal, depending on the wavelength of the excitation light. The slow component of PL was in details investigated. Time decay cures for different excitation (337.1 nm, 470 nm, and 550 nm) and emission (550, 650, 700, 800 and 860 nm) wavelengths and also for different excitation intensities were taken. All decay curves were fitted with a stretched exponential. The slow component of PL was proposed to be attributed to the radiative recombination on surfaces.

A high sensitive photoacoustic system has been developed to monitor the ethylene released by mature tomatoes and wheat seeds during germination as a response of fast effects of mechanical and thermal stress. Under normal conditions of temperature and pressure, the coronet removal yielded a significant increase of ethylene emission as compared to the local wounding of tomato tissues. To determine the temperature influence on ethylene emission rates, both tomatoes and germinating wheat seeds were investigated at cold treatment (4 degree(s)C) and at room temperature (22 degree(s)C). Early changes in ethylene released after imbibition in connection with the physiological results of germination were also monitored.

Silver and copper double activated phosphor samples were synthesized from zinc sulphide prepared by thiosulphate method and with a NaCl-MgCl₂ mixture as flux. The thermal treatment was performed in a protective atmosphere at 900 - 1100 degree(s)C. The samples were characterized by crystalline structure (XRD patterns) and luminescent properties (emission spectra, decay curves). An intensification effect of the copper green fluorescence by silver ions was put in evidence. Conditions for a good green emitting phosphor were established.

The molecular vibration temperature of the plasma from an interrupt arc discharge in air at atmospheric pressure and at current intensities in the range of 2 divided by 8 Amperes, using electronic and vibration bands of violet [B²(Sigma) ⁺ - X²(Sigma) ⁺] and red [A²(Pi) - X²(Sigma) ⁺] systems of the CN molecule was determined. At the equilibrium temperature of 6400 K, 27 lines of Ti, contained as impurity in coal electrode were found. These spectral lines were found in the 247 divided by 340 nm spectral range, having the upper levels of the excitation energies in the 3.60 divided by 5.69 eV range, in the neighborhood of the energy of dissociation of the CN molecule on the fundamental electronic state. Some considerations about the vibrational states populations are also made.

Infrared absorption spectroscopy can be performed at very high resolution by tunable diode laser (TDL) based optical systems for any gas with well resolved absorption spectra. In a double beam setup atmospheric trace gas concentration can be measured down to ppb levels. The analysis of trace gases may have useful applications in detecting chemicals in the human breath for non invasive medical diagnostic. The capability of TDL based breath analysis was well demonstrated by monitoring ammonia and methane. In the human body the formation of free radicals does induce oxidative degradation of polyunsaturated fatty acids (lipid peroxidation) which is a damage for cells and organs in the organism. Specific volatile hydrocarbons generated as end product by lipid peroxidation (LP) can be found inside circulating blood and expired breath. TDL based analysis of those specific hydrocarbons (ethane and pentane) in the expired breath can allow a non invasive assessment of the LP extent.

This paper presents a comprehensive review of the CO₂ laser ablation of biological tissue. Based on energy balance for modeling laser ablation, the thermal relaxation time and the ablation threshold are determined. Laser ablation of biological tissue is related to the spatial coherence of laser beams, so that the propagation of laser beams, the beam quality and the focusability of laser beams are taken into consideration. To achieve the ablation threshold, the laser irradiance in the focal zone is computed as a function of laser parameters. The advantages of pulsed operation of the CO₂ laser for minimum residual thermal damage of the tissue are stressed. The strengths and the weaknesses of the CO₂ laser ablation are finally discussed.

This paper reports a laser method for corneal structure investigation which allows to obtain images of corneal layers as well as information about dimensions of the endothelium and basal epithelium cells. The method's principle is based on the laser radiation reflection at the interface between ocular media having different refractive indices. So, the laser incident beam on the cornea is multiply reflected and refracted within it, since the cornea is a superposition of several transparent layers with different refractive indices. If observed on a screen, the radiation reflected by a certain corneal layer forms on it the image of corneal cell structure. Because of cornea curvature, the reflected beam which contains information about corneal structure--becomes strongly divergent; therefore the experimental set-up forms the cell images big enough to be seen directly by eye.

Excimer lasers are an excellent instrument for performing photorefractive keratotomy, PRK. The UV light from the laser causes an ablation of the cornea in proportion to the intensity of the light. The primary characteristic essential to successful PRK is the uniformity of the Top Hat, or working portion of the laser beam. In order for this intensity profile to be sufficiently uniform for PRK, it is essential to periodically measure the equality of the laser beam profile. This ensures that the laser continues to operate properly and provide the expected performance.

A normal and a tumoral chromatin radiosensitivity to an UV laser radiation was determined. The characteristics of these chromatin samples were established by the analysis of the absorption and emission spectra of chromatin complexes with a specific DNA ligand-ethidium bromide, by Scatchard representations of ligand binding to chromatin and by the Forster energy transfer efficiency determination between two fluorescent ligands coupled at chromatin: dansyl chloride and acridine orange. The effects of excimer laser beam with (lambda) equals 248 nm on chromatin structure were analyzed by the above methods and also by the establishment of the intrinsic chromatin fluorescence and of the excited state lifetimes of a specific DNA ligand.

Experiments were performed on five batches of inbred rats with Walker-256 carcinosarcoma receiving sole treatment photodynamic therapy (PDT), rMuIFN--gamma activated macrophages (AMO) or associated therapy (PDT+ AMO - A; PDT+ AMO - B) and the control batch (saline) consisting of animals with untreated Walker-256 tumors. These experimental observations demonstrate that `combined' photodynamic therapy with immunotherapy stimulates cell-mediated antitumoral activity, increased survival rates and reduces incidence of Walker-256 carcinosarcoma in rats.

A comparative study on four groups of patients which have been exposed to laser radiation was performed. Three wavelength were used (633, 670 and 830 nm). The fourth group received only laser placebo. Every group is composed by 20 people homogeneously selected from the point of view of age, sex and clinical and paraclinical parameters. The irradiation dose was kept almost the same, i.e. 15 J/cm². The dependence of subjective and objective indicators on the laser wavelength were put into evidence.

Low power laser (LPL) use in the treatment of arthrosic rheumatism is well known. From a total number of 280 patients with symptomatic spondylosis we finally selected 66, with changes of the EEG color mapping. These investigation was done before and after treatment in order to obtain an objective method to appreciate these results. The patients were splitted in laser group (36 patients treated with HeNe and IR diode LPL) and control group (30 patients treated with placebo laser). The results indicate a significant improvement of the symptoms at 77% of the patients from laser group as compared with 33% favorable results at the placebo laser. The EEG mapping improved at 58% patients from laser group as compared with 20% at the control group.

A Q-switched Nd:YAG laser beam and its second and fourth harmonics were focused onto the polished surface of dentine samples in order to compare the ablative effect for the three wavelengths. A photoacoustic technique is applied for the ablation threshold determination. The Scanning Electron Microscope images of the produced craters are investigated and the volume of ablated material is determined. The necessary optical constants for the ablation calculation are experimentally determined.

The damages of the complex of deoxyribonucleic acid (DNA) and proteins from chromatin, produced by the UV laser radiation and/or by treatment with a radiomimetic substance, bleomycin, were compared. The laser radiation and bleomycin effects on chromatin structure were determined by the static and dynamic fluorimetry of chromatin complexes with the DNA specific ligand-- proflavine and by the analysis of tryptophan chromatin intrinsic fluorescence. Time resolved spectroscopy is a sensitive technique which allows to determine the excited state lifetimes of chromatin--proflavine complexes. Also, the percentage contributions to the fluorescence of proflavine, bound and unbound to chromatin DNA, were evaluated. The damages produced by the UV laser radiation on chromatin are similar with those of radiomimetic substance action and consists in DNA and proteins destruction. The DNA damage degree has been determined. The obtained results may constitute some indications in the laser utilization in radiochimiotherapy.

The medical laser equipments made at NILPRP have been exploited intensively for more than 10 years at CMH. The availability and reliability of the first like-on equipment have increased, following improvements in optical delivery system and cooling circuit. This paper shows the impact of technical advances on the development of ophthalmologic laser therapy. Intraocular tumors pose special problems of diagnosis and treatment. Diagnostic methods include addition to systemic and ophthalmologic examinations, ancillary examinations, such as transillumination, fluorescence angiography, ultrasonography, radioactive phosphorus uptake tests, radiology, computerized tomography and fine-needle aspiration biopsy with cytological analyses. The enucleation of the involved eye used to be a generally accepted management of malignant tumors. Improved therapeutic methods such as photocoagulation and better surgical techniques now provide a variety of therapeutic alternatives. This study covers 31 cases of intraocular tumors that were managed either by Argon Laser photocoagulation and/or by Nd:YAG laser surgical treatment. Four cases were intraocular metastasse and 17 cases were primitive intraocular tumors. Argon laser therapy proved to be totally ineffective for intraocular metastasse but very adequate therapy for primitive tumors. Tumor extirpations (choroidal, cillary body or iris tumors) using Nd:YAG laser lancet proved to be more suitable than classic surgery.

In vitro laser-induced fluorescence (LIF) spectra and lifetimes of normal and atherosclerotic tissues are reported. The experimental arrangement conceived to measure LIF contained a 700 ps nitrogen pulsed laser (337.1 nm) and two quartz optical fibers to induce and respectively collect the fluorescence of normal and diseased samples. With UV laser excitation we found proeminent differences both in spectral and temporal range between normal artery and atherosclerotic plaques which was standard pathological classified in five types such as: normal artery, fibrous plaque, atherosclerotic plaque, calcified plaque and ulcerated plaque. As for statistics, the total number of measurements performed on each of the five mentioned types of tissues was 25.

We present static light scattering measurements of size-shape distributions of biological particles in suspension. Results are compared to the Rayleigh-Debye-Gans theory predictions. They are inverted to retrieve the geometrical parameters of the suspended particles and their size-distribution function. The inversion of data is performed by a combined method using normalized cubic B spline functions and linear programming, which is firstly applied to different sets of simulated data, to study its efficiency and stability in the presence of experimental noise.

In vitro (absorption spectroscopy) and in vivo (fluorescence microscopy) studies before and after the uptake of intraperitoneal injected Hematoporphyrin Derivative (HpD) were made in mice. The absorption spectrum of HpD is characterized by four bands in the visible region with decreasing absorption towards longer wavelengths (510 nm, 540 nm, 568 nm and 621 nm). These spectra were obtained only at low concentration (10^-5 M). After (15 - 30) minutes postirradiation (He-Ne laser, 1 mW) the features of curves were the same with those of nonirradiated samples but with a deplacement of wavelengths. The presence of laser emitting products was pointed out by fluorescence microscopy (cryostat section in fluorescence microscopy).

The medical laser applications use the thermal effects of laser irradiation. The present work contains applications of the thermovision. This method offers the following advantages recording and processing of the thermal distribution on the irradiated zone. The study has in view the development of an algorithm of work for an useful data base regarding the laser application in medicine. The experiments used Ar laser, laser diode and some kinds of biological tissues. The paper presents some thermal distributions before, during and after laser irradiation and the images processing.

In order to establish the low energy laser (LEL) effects on nervous tissue regeneration in clinical practice, we evaluated in double blind, placebo controlled study, the efficacy of LEL in the functional recovery of 46 patients with distal forearm post- traumatic nerve lesion, after surgical suture. The patients were divided into two groups: A-26 patients were treated with LEL; B- 20 patients, as control, were treated with placebo lasers and classical medical and physical therapy. Lasers used were: HeNe, 632.5 nm wavelength, 2 mW power, and GaAlAs diode laser, 880 nm wavelength, pulsed emission with an output power about 3 mW. Before, during and after the treatment, electromyography (EMG) and electroneurography (ENG) were done in order to measure objectively the efficacy of the treatment. We obtained good results after 4 - 5 months at 80.7% patients from group A and about the same results at 70% patients from group B, but after at least 8 months. The good results were noticed concerning the improvement of EMG and ENG registrations and on the involution of pain, inflammations, movements and force of the fingers. Finally we can say that the favorable results were obtained in at least half the time with LEL treatment faster than with classical therapy.

The authors tried to verify the efficacy of Low Power Laser (LPL) in scalp alopecia and crural ulcers of different causes. Laser used was (red diode, continuous emission, 8 mW power, wave length 670 nm spot size about 5 mm diameter on some points 1 - 2 minutes per point. We also use as control classical therapy. Before, during and after treatment, histological samples were done for alopecia. For laser groups (alopecia and ulcers) the results were rather superior and in a three or twice time shorter than control group. We conclude that LPL therapy is a very useful complementary method for the treatment of scalp alopecia and crural ulcers.

This paper presents the theoretical and practical solutions of infrared, heterodyne detection systems applied in the pollution monitoring, methane detection, industry as well as laser spectroscopy. The utilization of stabilized laser diodes, coherent pumped solid state lasers as well as CO₂ lasers with conversion of generation frequency covers the broad band of infrared region especially interesting for detection of different atmosphere pollutants or gas contaminants. Low cost heterodyne vibrometers, velocimeters or rangefinders can find wide industrial or metrological applications.

Integrated optical waveguides based on oxidized porous silicon were fabricated by means of traditional silicon technology. Near- field pattern and out-of-plane scattering losses were measured to characterize optical properties of the waveguides. Strong confinement of light within the core of the waveguides as well as optical losses of about 5 dB/cm have been demonstrated in the visible range. The achieved results make the waveguides promising in optoelectronics use.

Because the spatial beam structure is the most critical element of a laser, measurement of this beam structure is indispensable in laser design, development, and manufacture. Since measurement of the beam structure inside the cavity is impractical, if not impossible, the beam profile structure outside the laser provides the only real insight into cavity structure. It is critical that profile measurements outside the cavity be as precise and illuminating as possible. Electronic measurement of the output beam profile is the only method that gives sufficiently accurate and illuminating beam structure analysis.

The aim of this study is to present the results of the application of remote sensing techniques for seismic risk analysis, which estimates the geographic distribution, frequency, and intensity of seismic activity, without attempting to predict specific events. This method is based on the recognition of the active faults, which are defined as breaks along which movement has occurred in Holocene time (past 11,000 years). Remote sensing analysis and field studies of active faults can provide a geologic history that overcomes many of the shortcomings of instrumental and historic records.

The first successful attempt to integrate on-chip optical waveguides based on oxidized porous silicon and amorphous silicon photodetectors have been demonstrated. Buried channel waveguides were performed by thermal oxidation of porous silicon. Amorphous silicon photodetectors were fabricated on the waveguides. Different device structures as well as their performance attributes are exhibited. The devices were demonstrated to have photocurrent characteristics promising for optoelectronic applications.

In this paper we present the experimental results of the investigation of relief recording of the information with application of the media based on thermoplastic materials and synthesized organic photopolymers. We present also the results concerning the possibilities of strengthening of polymer media with the scope to improve mechanical properties of the relief image (hardness, strength, adhesive stability) and the possibilities to make copies by stamping method. Also we examine the possibility to increase the sensitivity of photothermoplastic media by addition of the injector chalcogenide layers.

The electrooptical properties of some SSFLC devices with high spontaneous polarization liquid crystals are presented. The switching time was determined as function of electric field strength and a.c. frequency. Using the switching time the rotational viscosity (gamma) _{$curly phi} was determined. The results are explained by considering the spectacular molecular relaxation, known as Goldstone mode. The surface stabilized ferroelectric liquid crystal (SSFLC) devices offer memory (bistable) capability, fast response speed and sharp threshold and have a variety of applications in electronics.

This work presents some contribution in the non-conventional optical components field. The idea is concerning to fluid optical components, having in view to elaborate a documentation--like a catalogue of optical fluids--for optical system design. The using of optical fluids represents a new method of attaining apochromatic color correction in refractive optical systems.

An optical fiber multiplexed image transmission system can be used in dangerous and low accessible environments, such as in nuclear or high explosion risk environments because the optical fiber cable is insensitive to the electromagnetic disturbances and, when an appropriate optical fiber is used, it withstands the gamma radiation. The system has the capability to simultaneously transmit, by using the video signals switch, the image from four CCD cameras placed in the dangerous environment to a remote surveillance center, at 2 km distance.

This paper presents an experimental study on the behavior of cylindrical piezoceramic transducers exposed to dynamic mechanical shocks. The piezoceramic materials under study are solid solutions of Pb(Zr_xTi_1-x)O₃ and present direct piezoelectric effect. In the laboratory were made experiments with cylinders of BaTiO₃ and PZT ceramics, for determination of their behavior at mechanical shocks. The shocks resistance of piezoceramic materials is essential in those applications that involve dynamic stress. The tests on ceramics have sought to establish the capacity of a piezoceramic element to resist at recurrent hits and to absorb energy.

The paper is the result of the studies made to establish criteria for the designing and the assessment of the optical systems for the night vision devices so that the ratio between the performances and the manufacture costs is best. These criteria were used to check optical systems of the existing night vision devices and to design new optical systems.

A bi-directional pointing and tracking system is needed in order to establish the optical link between two optical transceivers located in two separated points at the ground or on satellites. That usually suppose the presence of a separate laser transmitter an optical beacon used for pointing and tracking purposes. The major stages of the pointing and tracking process were analyzed based on a mathematical model presented in references. In order to increase the reliability of optical links a new optical beacon is purposed and, consequently a new pointing and tracking method is developed. This method requires only communication laser transmitters and uses their optical beams for pointing and tracking process, additionally giving the possibility to increase the signal to noise ratio at the communication receiver. A mathematical model of such a system is developed and an analysis of the method is performed.

Amorphous and hydrogenated (a-SiC:H) as well as crystalline silicon carbide are widespread materials for optoelectronic applications. In this paper, we studied the effect of laser/RF plasma jet treatment of a-SiC:H thin films deposited by Plasma Enhanced Chemical Vapor Deposition, on Si wafers. A Nd:YAG laser ((lambda) equals 1.06 micrometers , t_FWHM equals 14 ns, E₀ equals 0.015 J/pulse) was used with a fluence of 4 mJ/cm² incident on the sample, the number of pulses being varied. Plasma treatments were performed in a plasma jet generated by a capacity coupled RF discharge in N₂. Different analysis techniques were used to investigate the films, before and after the irradiation: X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. We followed the modification of their structure and composition as an effect of the laser/plasma treatment. A comparison with the excimer and also with the RF treatments was performed.

Radiation response of thick multimode Ge, P, F-doped quartz fiber has been examined after exposure to ⁶⁰Co gamma-source within a dose interval of 10 - 10⁷ Gy at a dose power of 2.3 and 24 Gy/s at 300 K. The induced transparency losses A at the wave length of 1.06 micrometers do not exceed 0.2 after a dose of 10⁶ Gy and reach a saturation, while the fibers are closed for visible light after a smaller dose. Varying focus and an angle of leading a probe light beam in fiber, the core modes were found to close at a dose of 10⁴ Gy due to radiation induced color centers of Ge and non-bridging oxygen O^-, and the clad modes were suppressed at 500 Gy by the expense of Al impurity color centers.

The ferroelectric/semiconductor heterostructures were fabricated by sol-gel deposition of lead titanate (PT) thin films on a single-crystalline p-type Si wafers. The PT films were crystallized by a conventional thermal annealing for 30 min at temperatures ranging from 575 degree(s)C to 675 degree(s)C. Current-voltage and capacitance-voltage characteristics show a hysteresis which can be due to the spontaneous polarization of PbTiO₃. The current-voltage characteristics exhibit a diode behavior while the capacitance-voltage exhibits a large memory window, up to 3.5 V, for the films annealed at 600 - 650 degree(s)C. At the illumination with modulated light, a.c. photovoltage was detected on a broad range of wavelengths (0.35 divided by 4 micrometers ) for all samples. The spectral distribution of the photoelectric signal in the UV-Vis- IR domain shows two local maxima. A model is proposed to explain the observed experimental results.

The notorious implication of integrated optics in the nowadays communication systems makes more interesting the development of optical integrated devices and circuits. The evolution of the communication systems was sustained by the integrated optics and it is obvious that the actual interests in the optical communications are also transferred and adapted to integrated optics. The presentation of actual state-of-the-art in this field is a good opportunity both for an evaluation on the above mentioned evolution and for discerning the actual trends and their perspectives. These trends, guided by applicative goals, have to be discussed not only from the theoretical point of view but also from a practical one.

This paper reports on the optical properties of polycrystalline p-type In_xGa_1-xSb (x equals 0.20) over the wavelength range 15 - 30 micrometers , at room temperature. The material was obtained by direct synthesis from the elements and rapidly crystallized following a particular temperature regime. Transmittance and reflectance measurements were performed at room temperature by using a SPECORD M80 spectrophotometer. From the resulted values we calculated the absorption coefficient (alpha) as a function of the photon energy. Considerations are made concerning the peculiarities involved by the polycrystalline structure and the surface imperfections on the absorption phenomena over the mentioned wavelength range.

A mode of quantic detection for noncoherent optical radiation as noise limit is presented. Using the representation on coherent state of density matrix operators ((rho) ) and of detection operators ((pi) ), the detection probability (Q_d), false alarm probability (Q_o) and signal-noise ratio (S/Z), are estimated, as function of the number of freedom degrees of temporal oscillation modes (M_t) and of the spatial oscillation modes (M_s). A validation algorithm of statistical hypotheses, resulted from noncoherent optical field analysis, is made using Newman-Pearson criterion.

The refractive index distribution is a key parameter not only to characterize the technological process but also for any integrated optical simulator. In this paper we propose a new algorithm to reconstruct the refractive index profile from the near-field measurements. The technique is based on the matching of the measured intensity profile with a computed one, varying the maximum index change and the diffusion depth.

In a unitary approach generally used in quantum optics, we consider Lindblad's Markovian master equation and the non- Markovian master equation of Ford, Lewis and O'Connell. We show that the second-order master equation in the hierarchy obtained from a Krylov-Bogoliubov expansion corresponds to the Born approximation. By time averaging, and neglecting the rapidly varying terms, Lindblad's master equation is obtained. With these two equations, we calculate the decay spectrum. We find that for rather low dissipated energies, only the non-Markovian master equation provides correct results. Based on the independent oscillator model of the dissipative coupling, explicit expressions of the dissipative coefficients are obtained.

This paper presents an experimental study on the behavior of piezoceramics type PZT, having a high compliance, and their application for an optoelectronic micropositioner device with piezoceramic transducer. The piezoelectric ceramics are crystallite conglomerate ferroelectrics materials with random orienting. In the laboratory we have realized PZT ceramics with various additions (Ni, Bi, Mn), presenting high compliance, for optoelectronic micropositioning device in micrometry displacements. The experimental transducers, realized like stacks of 30 divided by 35 pieces of PZT thin disks, supplied with 0 divided by 1000 V voltages, have produced 0 divided by 15 micrometers displacements.

In this paper an optical evaluation of the system Ni,Bi/Cu,ITO/glass system, prepared by electrochimical method is presented. Among various factors that affect the optical and structural properties of the multistructure systems we focus on the influence of the substrate and the interfacial oxidic layers. To this end we used the Spectroellipsometric (SE) method in VIS- NIR spectral range. The SE results show that the electrochemical deposited films (Ni,Bi) are porous and their refractive index depends strongly on the substrate.

The integration of digital remote sensing data from either airborne or spaceborne platforms and normal line or thematic maps has become increasingly significant to a varied field of applications, from geology to municipal mapping. To take full advantage of this data source, it must be overlayed to existing map data. The geometry and projection information must be equivalent, in other words they must be an orthogonal projection or correlation between the point on the ground and some reference surface. This process is referred to as rectification. The output satellite or airphoto images are referred to as orthorectified images or ortho images. The particular data we have used--SAR (Synthetic Aperture Radar) have several characteristics which we had to take into account in order to produce the orthorectified images. The main problem is the geometric distortion (layover, shadowing effects) due to the oblique viewing of the antenna. Another problem met was the `speckle' type perturbation, due to the coherence of the radar signal. An orthorectification procedure for radar data (SAR-ERS-1) over a mountainous zone in Romania (Buzau) is presented, also a registration procedure with optical (Landsat TM) data and a complementarity study.