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25 January 2000 Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions
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Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375366
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation
Abstract
The contribution have been devoted the construction of effective quadrupole coupling operator for quasidegenerate vibrational levels of polyatomic molecules and the reduction of the laser. The indeterminacy problem of the parameters in the effective vibrational-rotational HeffVR and quadrupole Weff Hamiltonians for the cases of accidental resonances linked with various groupings of vibrational- rotational interactions (problem of grouping uncertainty) are considered. The problem of the reduction of Heff equals HeffVR + Weff is discussed. The case of the Coriolis-type, accidental resonances have been considered more detail. New representation of Heff equals HeffVR + Weff for isolated vibration levels in form of angular moments only is presented.
© (2000) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Vladimir M. Mikhailov "Effective quadrupole coupling operator for quasi-degenerate vibrational states of polyatomic molecules in the theory of linked ordering schemes of rovibrational interactions", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375366
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