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25 January 2000 Experimental bandshapes of the ν3 band of CH3F in helium: the role of interbranch and intrabranch line mixing
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Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375388
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation
Abstract
We measured a series of absorption profiles of the v3 band of CH3F perturbed by helium. The measurements were performed at room temperature for helium pressures from 1 to 90 atm. We observe significant deviations of measured profiles with respect to those calculated as a sum of lines having Lorentzian shapes. To interpret the observed deviations, we consider various models of line mixing. The calculations performed in the ECS approximation provide the most reasonable agreement with the measured band shapes reproducing the existing data on line broadening coefficients within the limits of experimental uncertainty. Special attention is paid to the analysis of the differences of interbranch and intrabranch line mixing, that is to the structure of relaxation matrix.
© (2000) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
F. Thibault, J. Boissoles, I. M. Grigor'ev, N. N. Filippov, and M. V. Tonkov "Experimental bandshapes of the ν3 band of CH3F in helium: the role of interbranch and intrabranch line mixing", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375388
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