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25 January 2000 IR spectroscopy of interhalides XF3 and XF5 (X = Cl, Br)
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Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375372
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation
Abstract
Interhalogens XF3 and XF5 (X equals Cl,Br) are widely used for reprocessing of nuclear materials, in electronic and iron-and-steel industries. At the same time XF3 and XF5 may be regarded among most dangerous components in the plumes of emergency ejections of these manufactures. The Cl and Br fluorides interact actively with atmospheric gases resulting in the formation of hydrogen halogen, Cl and Br oxyfluorides and oxides which are transformed into stable complexes (HHal)x...(H2O)y, where Hal equals F, Cl, Br; x + y >= 2. A study into reaction mechanisms with a participation of the XF3 and XF5 compounds, their secondary compounds and the applicability of the remote laser control techniques requires comprehensive information on vibration spectra of interhalogens.
© (2000) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Shavkat Sh. Nabiev "IR spectroscopy of interhalides XF3 and XF5 (X = Cl, Br)", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375372
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