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Amine-epoxy based gel actuators have been made since this chemistry allows the small volume gels to be made easily and is expected to provide enough strength for practical use with highly crosslinked networks. In this study, a small drop of cationic polyelectrolyte gel was prepared by crosslinking of trifunctional polyetheramines with ethylene glycol diglycidyl ether. The response of these materials to electrical stimuli, pH and metal ions is controlled by the crosslink density and ionic strength of medium. When the gels contact a platinum anode, positive charges are generated on the amine groups and the ionic repulsion causes the swelling. Reversing current neutralizes amines and the hydrogen bonding interaction causes a volume collapse. These gels show large and rapid swelling in response to an electrical and chemical input on a sub-millimeter scale.
Yuka Yoshioka andPaul D. Calvert
"Electrically driven miniature hydrogels as muscle-like actuators", Proc. SPIE 4329, Smart Structures and Materials 2001: Electroactive Polymer Actuators and Devices, (16 July 2001); https://doi.org/10.1117/12.432648
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Yuka Yoshioka, Paul D. Calvert, "Electrically driven miniature hydrogels as muscle-like actuators," Proc. SPIE 4329, Smart Structures and Materials 2001: Electroactive Polymer Actuators and Devices, (16 July 2001); https://doi.org/10.1117/12.432648