Conjugated polymer composites for use in electrophosphorescent light-emitting diodes

Xiong Gong; Wanli Ma; Jacek C. Ostrowski; Guillermo C. Bazan; Daniel Moses; Alan J. Heeger

doi:10.1117/12.515221

16 February 2004 Conjugated polymer composites for use in electrophosphorescent light-emitting diodes

Xiong Gong, Wanli Ma, Jacek C. Ostrowski, Guillermo C. Bazan, Daniel Moses, Alan J. Heeger

Proceedings Volume 5214, Organic Light-Emitting Materials and Devices VII; (2004) https://doi.org/10.1117/12.515221
Event: Optical Science and Technology, SPIE's 48th Annual Meeting, 2003, San Diego, California, United States

Abstract

High performance electrophosphorescent light emitting diodes (LEDs) were demonstrated by using conjugated polymers, poly(9,9-dioctylfluorenyl-2,7-diyl) (PFO), PFO end-capped with hole-transporting moieties (HTM), PFO-HTM, and PFO end-capped with electron-transporting moieties (ETM), PFO-ETM, as the hosts and the organometallic emitter, tris-[2,5-bis-2'-(9,9'-dihexylfluorene) iridium] [Ir(HFP)₃] as the guest. Electrophosphorescent LEDs fabricated from PFO, PFO-HTM, and PFO-ETM as the hosts emit red light with turn-on voltage around 5V, luminances (L) of 2040 cd/m², 1937 cd/m² and 2487 cd/m² at 290 mA/cm² (16 V), and luminance efficiencies (LE) of 1.40 cd/A, 1.38 cd/A and 1.80 cd/A at 4.5 mA/cm² for PFO, PFO-HTM, and PFO-ETM, respectively. The results demonstrate that high performance electrophosphorescence can be obtained from conjugated polymer-based LEDs that are fabricated by processing the active materials directly from solution.

Citation Download Citation

Xiong Gong, Wanli Ma, Jacek C. Ostrowski, Guillermo C. Bazan, Daniel Moses, and Alan J. Heeger "Conjugated polymer composites for use in electrophosphorescent light-emitting diodes", Proc. SPIE 5214, Organic Light-Emitting Materials and Devices VII, (16 February 2004); https://doi.org/10.1117/12.515221

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