Hydrogen sulfide absorption spectrum in the 5700-6600 cm-1 spectral region

L. R. Brown; O. V. Naumenko; E. R. Polovtseva; Leonid N. Sinitsa

doi:10.1117/12.545192

12 January 2004 Hydrogen sulfide absorption spectrum in the 5700-6600 cm^-1spectral region

L. R. Brown, O. V. Naumenko, E. R. Polovtseva, Leonid N. Sinitsa

Proceedings Volume 5311, 14th Symposium on High-Resolution Molecular Spectroscopy; (2004) https://doi.org/10.1117/12.545192
Event: 14th Symposium on High-Resolution Molecular Spectroscopy, 2003, Krasnoyarsk, Russian Federation

Abstract

High resolution FT absorption spectrum of H₂S from 5700 to 6600 cm^-1was experimentally recorded and theoretically treated. As a result of the spectrum assignment 1100 precise energy levels were derived for the 2nd hexad interacting states of H₂³²S, H₂³³S, and H₂³⁴S isotope species including the highly excited (050) state. These energy levels were modeled using Watson-type rotational Hamiltonian and taking into account Coriolis, Darling-Dennison and weak Fermi-resonance interactions inside polyad of interacting states. An average accuracy of the energy levels fitting is of 0.0019 cm^-1for the main isotope species. New evaluation of the band origin of the dark (012) state E_v = 6385.299cm^-1is obtained from the fitting process which agrees well with recent prediction by Naumenko et al. (J. Mol. Spectrosc. 50, 100-110 (2001)). Precise line intensity measurements were performed for more than 1200 absorption lines with accuracy varying from 1 to 7%. These intensities were modeled within 3.3% using wavefunctions derived in the process of the energy levels fitting. The transformed transition moment expansion with 29 terms for 1088 intensities was used. Detailed and accurate H₂S absorption line list was generated in the HITRAN format for the analyzed spectral region.

Citation Download Citation

L. R. Brown, O. V. Naumenko, E. R. Polovtseva, and Leonid N. Sinitsa "Hydrogen sulfide absorption spectrum in the 5700-6600 cm^-1spectral region", Proc. SPIE 5311, 14th Symposium on High-Resolution Molecular Spectroscopy, (12 January 2004); https://doi.org/10.1117/12.545192

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