Paper
20 September 2005 Solid-state molecular sensors (SSMS) based on confined III-IV-V2 multi-functional heterostructures
Nikolaus Dietz, Frank Madarasz, Ramarao Inguva
Author Affiliations +
Abstract
Nonlinear confined (optical and/or electrical) heterostructures based on III-IV-V2 chalcopyrite (CP) thin films and/or embedded CP materials offer unique advantages over group III-V and IV linear structures. These stem from the birefringent nature and the lower crystal symmetry of the CP semiconductors. As an example, this property is responsible three-wave nonlinear parametric processes (a second-order nonlinear effect) and very high values of the second-order hyperpolarizabilities. The recent discovery of room-temperature ferromagnetism in diluted magnetic CP semiconductors adds an additional functionality to this material system that makes possible the construction of novel magneto-optical device structures based on ferromagnetic nanocomposites and confined ferromagnetic heterostructures, which can be embedded in confined birefringent layers. Such structures are the basic elements for advanced "Solid-State Molecular Sensor" (SSMS) device structures. Rugged, miniaturized SSMS structures can be constructed which are based on a unique, optically confined birefringent, group II-IV-V2 CP heterostructure technology. This system identifies target chemicals and biological molecules in real-time under ambient conditions. It can detect and discriminate between numerous and varied molecular species by employing resonant phase- and/or amplitude sensitive detection over a large, tunable spectral range. The SSMS can be made sensitive to a specific group of molecules with appropriate phase matching conditions. Its response is unlike that of a linear waveguide sensor in two primary areas: change of frequency output, and intensity of the output light generated. Both signals are generated in a nonlinear second harmonic generation process sensitive to small changes in the phase matching conditions. Potential applications include compact ultra-sensitive sensors, nonlinear optical modulators, magnetic photonic crystals, magneto-optical switches, detectors, and spin electronic devices.
© (2005) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Nikolaus Dietz, Frank Madarasz, and Ramarao Inguva "Solid-state molecular sensors (SSMS) based on confined III-IV-V2 multi-functional heterostructures", Proc. SPIE 5912, Operational Characteristics and Crystal Growth of Nonlinear Optical Materials II, 59120J (20 September 2005); https://doi.org/10.1117/12.613191
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KEYWORDS
Sensors

Heterojunctions

Waveguides

Phase matching

Second-harmonic generation

Silicon

Ferromagnetics

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