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13 September 2007 Modulated conjugation for record-high intrinsic hyperpolarizabilities
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Abstract
The effects of a complex hybrid conjugation path in linear molecules as an strategy to optimize the intrinsic first hyperpolarizability is investigated. A series of 7 novel chromophores with different hybrid conjugation paths were synthesized and characterized. Hyper-Rayleigh scattering experiments confirm that complex hybrid conjugation paths, including benzene, thiophene and/or thiazole rings in combination with azo- and/or ethenyl-linkages, between a dihydroxyethylamino donor group and different acceptor groups, results in an enhanced intrinsic hyperpolarizability that exceed the apparent limit for two of the chromophores.
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Javier Pérez-Moreno, Koen Clays, Mark G. Kuzyk, Yuxia Zhao, Yuquan Shen, Ling Qiu, and Juming Hao "Modulated conjugation for record-high intrinsic hyperpolarizabilities", Proc. SPIE 6653, Linear and Nonlinear Optics of Organic Materials VII, 66530W (13 September 2007); https://doi.org/10.1117/12.730845
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