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30 April 2008Commercially available high-throughput Dip Pen Nanolithography
Dip Pen Nanolithography® (DPN®) is an inherently additive SPM-based technique which operates under ambient
conditions, making it suitable to deposit a wide range of biological and inorganic materials. Massively parallel two-dimensional
nanopatterning with DPN is now commercially available via NanoInk's 2D nano PrintArrayTM, making
DPN a high-throughput, flexible and versatile method for precision nanoscale pattern formation. By fabricating 55,000
tip-cantilevers across a 1 cm2 chip, we leverage the inherent versatility of DPN and demonstrate large area surface
coverage, routinely achieving throughputs of 3x107 μm2 per hour. Further, we have engineered the device to be easy to
use, wire-free, and fully integrated with the NSCRIPTOR's scanner, stage, and sophisticated lithography routines. In this
talk we discuss the methods of operating this commercially available device, subsequent results showing sub-100 nm
feature sizes and excellent uniformity (standard deviation < 16%), and our continuing development work. Simultaneous
multiplexed deposition of a variety of molecules is a fundamental goal of massively parallel 2D nanopatterning, and we
will discuss our progress on this front, including ink delivery methods, tip coating, and patterning techniques to generate
combinatorial libraries of nanoscale patterns. Another fundamental challenge includes planar leveling of the
2D nano PrintArray, and herein we describe our successful implementation of device viewports and integrated software
leveling routines that monitor cantilever deflection to achieve planarity and uniform surface contact. Finally, we will
discuss the results of 2D nanopatterning applications such as: 1) rapidly and flexibly generating nanostructures; 2)
chemically directed assembly and 3) directly writing biological materials.
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J. R. Haaheim, E. R. Tevaarwerk, J. Fragala, R. Shile, "Commercially available high-throughput Dip Pen Nanolithography," Proc. SPIE 6959, Micro (MEMS) and Nanotechnologies for Space, Defense, and Security II, 69590I (30 April 2008); https://doi.org/10.1117/12.777219