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It was shown that broadband near infrared fluorescence in recently discovered in Bi-doped glasses is not specific to Biions.
Germanate glasses doped with different 6p (Bi, Pb) and 5p (Sn, Sb) ions (co-doped with Al) exhibit similar behavior. The centers can be characterized by 4 peaks in the excitation-emission plots. The decay of fluorescence (excited with short laser pulse at 800 nm and 532 nm) has complex behavior. The components of the decay are in the nsto ms- range and they have different temperature dependences. To our opinion, existing models of optical center suggested earlier should be revised to agree with new data.
Mikhail Sharonov,A. Bykov, andR. R. Alfano
"Study of optical centers with near-infrared emission in germanate
glasses doped with 6p (Bi, Pb) and 5p (Sn, Sb) ions", Proc. SPIE 7193, Solid State Lasers XVIII: Technology and Devices, 71932F (27 February 2009); https://doi.org/10.1117/12.808000
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Mikhail Sharonov, A. Bykov, R. R. Alfano, "Study of optical centers with near-infrared emission in germanate glasses doped with 6p (Bi, Pb) and 5p (Sn, Sb) ions," Proc. SPIE 7193, Solid State Lasers XVIII: Technology and Devices, 71932F (27 February 2009); https://doi.org/10.1117/12.808000