The pulsed discharge in oxygen and its mixtures to produce singlet delta oxygen has been studied experimentally at gas
pressure of 30~ 936mBar. As singlet sigma state of oxygen O2(b1Σg+) and atomic oxygen O have great influence on the
yield of singlet delta oxygen O2(a1▵g), the visible spectrum of O2(b1Σg+) at 762nm and O at 778nm have been measured,
and the effects of argon, helium and carbon monoxide have been discussed. The electric stability was better in O2-He
than in O2-Ar mixtures, while it could be increased quickly with a small amount of CO. In O2-He mixtures more oxygen were decomposed than in O2-Ar mixtures, while adding CO the decomposition was reduced, the amount of atomic
oxygen was decreased, and the O2(b1Σg+) was increased comparatively. The time-resolved spectrum of the plasma has also been measured. The life-time of atomic oxygen was longer than O2(b1Σg+)'s, and it could be shorten with argon.
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