Spectroscopic detection of metals ions using a novel selective sensor

D. Peralta-Domínguez; G. Ramos-Ortiz; J. L. Maldonado; M. Rodriguez; M. A. Meneses-Nava; O. Barbosa-Garcia; R. Santillan; N. Farfan

doi:10.1117/12.903261

25 October 2011 Spectroscopic detection of metals ions using a novel selective sensor

D. Peralta-Domínguez, G. Ramos-Ortiz, J. L. Maldonado, M. Rodriguez, M. A. Meneses-Nava, O. Barbosa-Garcia, R. Santillan, N. Farfan

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Proceedings Volume 8011, 22nd Congress of the International Commission for Optics: Light for the Development of the World; 80115C (2011) https://doi.org/10.1117/12.903261
Event: International Commission for Optics (ICO 22), 2011, Puebla, Mexico

Abstract

Colorimetric chemosensors are simple, economical and practical optical approach for detecting toxic metal ions (Hg²⁺, Pb²⁺, Ni²⁺, etc.) in the environment. In this work, we present a simple but highly specific organic compound 4-chloro-2-((E)-((E)-3-(4-(dimethylamino)phenyl)allylidene)amino)phenol (L1) that acts as a colorimetric sensor for divalent metal ions in H2O. The mechanism of the interaction between L1 and various metal-ions has been established by UV-vis absorption and emission spectroscopic experiments that indicate favorable coordination of metal ions with L1 in different solvents. Experimental results indicate that the shape of the electronic transition band of L1 (receptor compound) changed after the interaction with divalent metal-ions, such as Hg²⁺, Pb²⁺, Mn²⁺, Co²⁺, Cu²⁺, and Ni²⁺ in aqueous solution. We found that L1 have a considerable selectivity for Ni²⁺ ions, even in presence of other metals ions when mixtures of DMSO/H₂O as are used as solvents. L1, which has been targeted for sensing transition metal ions, exhibits binding-induced color changes from yellow to pink observed even by the naked eye in presence of Ni²⁺ ions.

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D. Peralta-Domínguez, G. Ramos-Ortiz, J. L. Maldonado, M. Rodriguez, M. A. Meneses-Nava, O. Barbosa-Garcia, R. Santillan, and N. Farfan "Spectroscopic detection of metals ions using a novel selective sensor", Proc. SPIE 8011, 22nd Congress of the International Commission for Optics: Light for the Development of the World, 80115C (25 October 2011); https://doi.org/10.1117/12.903261

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KEYWORDS

Ions

Metals

Absorption

Sensors

Nickel

Molecules

Luminescence

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