Paper
19 August 2011 Investigation on luminescence properties of Er3+-Yb3+-Tm3+ co-doped Gd2O3 hollow microspheres
Fang Xu, Wan-lei Han, Xiao-bo Liu, Ying-lin Song
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Abstract
The Gd2O3 hollow microspheres have been successfully fabricated via carbonaceous polysaccharide microspheres as templates and urea as a precipitating agent, which involved the deposition of an inorganic coating on the surface of carbon microsphere, followed by heat treated 800°C for 4h. The obtained high uniform Gd2O3 microspheres with a spherical shape and hollow structure are uniform in size and distribution. The possible mechanism of evolution from glucose to carbonaceous polysaccharide microspheres and the chemical reaction of each step to form the final hollow spheres are proposed. The rare earth ion Ln3+ doped Gd2O3 (Ln = Er, Yb and Tm) hollow microspheres show bright up-conversion luminescence with different colors coming from different activator ions under ultraviolet or 980 nm light excitation, which may open new possibilities to synthesize other hollow spherical materials and extend their applications.
© (2011) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Fang Xu, Wan-lei Han, Xiao-bo Liu, and Ying-lin Song "Investigation on luminescence properties of Er3+-Yb3+-Tm3+ co-doped Gd2O3 hollow microspheres", Proc. SPIE 8192, International Symposium on Photoelectronic Detection and Imaging 2011: Laser Sensing and Imaging; and Biological and Medical Applications of Photonics Sensing and Imaging, 81922Y (19 August 2011); https://doi.org/10.1117/12.900791
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KEYWORDS
Ions

Luminescence

Nanocrystals

Absorption

Crystals

Diffraction

Gadolinium

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