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7 March 2014Calibrating bimetallic grayscale photomasks to photoresist response for precise micro-optics fabrication
Microfabricating high resolution micro-optics structures requires shape control to <1/8th wavelength (~60nm) in both
vertical and horizontal surface precision. Grayscale bimetallic photomasks are bi-layer thermal resists consisting of two
thin layers of Bi-on-Indium or Tin-on-Indium. A focused laser spot creates a thermal metal oxide with a controllably
transparency set by the beam power of optical density from ~3OD (unexposed) to <0.22OD (fully exposed). A directwrite
raster-scan photomask laser system with a CW Argon-ion laser at 514nm for the bimetallic writing and 457nm
line for measuring the OD change used a feedback-controlled Gaussian beam to achieve 256-level grayscale masks.
Setting the graylevels required to achieve uniform vertical steps in the photoresist requires adjustment in transparency
based on the exact response curves of a given resist/development process. An initial model is developed using the
classic resist threshold dose exposure D0 and dose to clear Dc creating a power law relation between the required
exposure dose for each thickness step and the mask transparency. However real resists behave differently than the
simple model near the threshold requiring careful calibrating of mask graylevel transparencies with the photoresist
response curve for a given resist/development process. Test structures ranging from steps to ramps and complex
patterns were examined via both SEM and profilometry from the resulting bimetallic grayscale masks. Secondary
corrections modify the needed bimetallic OD due to the exposure source spectrum differences from the 457nm
measurement. This enhances the patterning of micro-optic and 3D MEMS structures.
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Glenn H. Chapman, Reza Qarehbaghi, Santiago Roche, "Calibrating bimetallic grayscale photomasks to photoresist response for precise micro-optics fabrication," Proc. SPIE 8973, Micromachining and Microfabrication Process Technology XIX, 897307 (7 March 2014); https://doi.org/10.1117/12.2041429