Bio-hybrid integrated system for wide-spectrum solar energy harvesting

Kathleen Martin; Matthew Erdman; Hope Quintana; John Shelnutt; John Nogan; B. Swartzentruber; Julio Martinez; Olga Lavrova; Tito Busani

doi:10.1117/12.2040747

7 March 2014 Bio-hybrid integrated system for wide-spectrum solar energy harvesting

Kathleen Martin, Matthew Erdman, Hope Quintana, John Shelnutt, John Nogan, B. Swartzentruber, Julio Martinez, Olga Lavrova, Tito Busani

Author Affiliations +

Proceedings Volume 8983, Organic Photonic Materials and Devices XVI; 89831D (2014) https://doi.org/10.1117/12.2040747
Event: SPIE OPTO, 2014, San Francisco, California, United States

Abstract

An integrated hybrid photovoltaic-thermoelectric system has been developed using multiple layers of organic photosensitizers on inorganic semiconductors in order to efficiently convert UV-visible and IR energy into electricity. The hot anode of n-type ZnO nanowires was fabricated using a thermal process on pre-seeded layer and results to be crystalline with a transmittance up to 92 % and a bandgap of 3.32 eV. The visible-UV light-active organic layer was deposited between the anode and cathode at room temperature using a layer-by-layer deposition onto ITO and ZnO and Bi₂Te₃ nanowires from aqueous solution. The organic layer, a cooperative binary ionic (CBI) solid is composed of oppositely charged porphyrin metal (Zn(II) and Sn(IV)(OH‑)2) derivatives that are separately water soluble, but when combined form a virtually insoluble solid. The electron donor/acceptor properties (energy levels, band gaps) of the solid can be controlled by the choice of metals and the nature of the peripheral substituent groups of the porphyrin ring. The highly thermoelectric structure, which acts as a cold cathode, is composed of p-type Bi2Te3 nanowires with a thermoelectric efficiency (ZT) between ~0.7 to 1, values that are twice that expected for bulk Bi2Te3. Efficiency of the integrated device, was found to be 35 at 0.2 suns illumination and thermoelectric properties are enhanced by the charge transfer between the CBI and the Bi₂Te₃ is presented in terms of photo- and thermogenerated current and advantages of the low cost fabrication process is discussed.

Citation Download Citation

Kathleen Martin, Matthew Erdman, Hope Quintana, John Shelnutt, John Nogan, B. Swartzentruber, Julio Martinez, Olga Lavrova, and Tito Busani "Bio-hybrid integrated system for wide-spectrum solar energy harvesting", Proc. SPIE 8983, Organic Photonic Materials and Devices XVI, 89831D (7 March 2014); https://doi.org/10.1117/12.2040747

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available

Members: $17.00

Non-members: $21.00 ADD TO CART

PROCEEDINGS
6 PAGES

DOWNLOAD PAPER SAVE TO MY LIBRARY

GET CITATION

RIGHTS & PERMISSIONS

Get copyright permission Get copyright permission on Copyright Marketplace

KEYWORDS

Zinc oxide

Solar energy

Thermoelectric materials

Photovoltaics

Solids

Solar cells

Nanowires

Show All Keywords

Keywords/Phrases

Search In:

Publication Years