Strong photoluminescence characteristics of sulforhodamine B attached on photonic crystal

Byoung-Ju Kim; Kwang-Sun Kang

doi:10.1117/12.2061453

27 October 2014 Strong photoluminescence characteristics of sulforhodamine B attached on photonic crystal

Byoung-Ju Kim, Kwang-Sun Kang

Proceedings Volume 9181, Light Manipulating Organic Materials and Devices; 918117 (2014) https://doi.org/10.1117/12.2061453
Event: SPIE Organic Photonics + Electronics, 2014, San Diego, California, United States

Abstract

The optical properties of sulforhodamine B (SRH) impregnated in photonic crystal by two step synthetic processes including a urethane bond formation between a 3-isocyanatopropyl triethoxysilane (ICPTES, -N=C=O) and a SRH with elevated temperature in pyridine and hydrolysis-condensation reactions between synthesized ICPTES/SRH (ICPSRH) and tetraethoxyorthosilicate (TEOS) in NH4OH. The monodisperse silica spheres impregnated the ICPSRH (ICPSRHS) are fabricated. The reduction of the absorption peak at 2270 cm^-1 representing asymmetric stretching vibration of –N=C=O indicates the progress of the reaction and new absorption peak at 1712 cm^-1 characterizing –C=O stretching vibration indicates the formation of urethane bond. The UV-visible absorption spectra show the broadened spectral line width by intermolecular interaction. The photoluminescence (PL) peak of the SRH in methanol shows a hypsochromic shift with the increase the excitation wavelength. However, the PL peak for the ICPSRH exhibits a bathochromic shift as the excitation wavelength increases. The PL peak for the ICPSRH shows no hypsochromic or bathochromic shift. The PL peaks for SRH in methanol, ICPSRH and ICPSRHS are at 568, 598 and 572 nm, respectively. The main cause of the PL peak shift is due to the intermolecular interaction.

Citation Download Citation

Byoung-Ju Kim and Kwang-Sun Kang "Strong photoluminescence characteristics of sulforhodamine B attached on photonic crystal", Proc. SPIE 9181, Light Manipulating Organic Materials and Devices, 918117 (27 October 2014); https://doi.org/10.1117/12.2061453

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available