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5 September 2015Structural dynamics in azobenzene liquid crystal polymer films studied by microscopic and time-resolved technique
We studied the photo-induced dynamics in a LC polymer film including azobenzene by using a time-resolved and a
microscopic technique. The film was confined in a liquid crystal cell, while it is a photomobile film under a free standing
condition, which is triggered by the photoisomerization of azobenezene. From the result of the time-resolved
measurements, the change inside the film induced by UV irradiation was highly anisotropic polarization change.
Microscopic observation revealed that the film was consisted of ordered and disordered region with a patched structure,
and the UV induced change was travelled in the ordered region on the order of seconds.