Yonggang Jiang, Jianchao Fu, Junfeng Pan, Zhonglie An, Jun Cai, Deyuan Zhang
Journal of Micro/Nanolithography, MEMS, and MOEMS, Vol. 14, Issue 01, 014502, (February 2015) https://doi.org/10.1117/1.JMM.14.1.014502
TOPICS: Silicon, Nanolithography, Etching, Gold, Reactive ion etching, Nanostructures, Chemical species, Scanning electron microscopy, Nanofabrication, Photomasks
Diatom frustules exhibit various sophisticated shapes with highly ordered hierarchical porous nanostructures, which are promising for applications in the biomimetic fabrication of nanostructured materials. We propose a universal biopattern transfer process for the fabrication of functional micro/nanostructures using diatom frustules as the biotemplates. Porous silicon microcylinders with a thickness of 20 μm are fabricated by deep reactive ion etching of a silicon substrate, which is covered by a layer of diatom frustules. With a similar process, a fast atom beam technique is used to etch the silicon substrate and silicon nanolattices are obtained. By depositing a thin layer of gold film on the diatom bonded silicon substrate, followed by releasing the diatom frustules by diluted HF, gold nanodisks with a thickness of 30 nm are successfully fabricated. The nanodisk array arranges in diamond or radial patterns, replicating the nanostructure of diatom frustules. In addition, a parylene nanodot array is also demonstrated using this diatom-based biopattern transfer process.