In this paper we have demonstrated successfully for the first time, a simple but efficient and reliable approach for the
growth of multi walled carbon nanotubes (MWCNTs) with high degree of crystallinity, purity and density under a wide
range of growth parameters. Multi-walled carbon nanotubes (MWCNTs) were synthesized at 800 - 950°C by thermal
chemical vapor deposition (TCVD) method using a thin nickel film as catalyst and methane gas as carbon source. In this
process, two substrates were placed in a long alumina boat inside a double-heater TCVD. One of the substrates was
covered with a short upside down alumina boat. The prepared nanotubes were characterized by scanning electron
microscopy (SEM) and field emission scanning electron microscopy (FESEM) and it was found that, CNT growth on
the covered substrate was improved in terms of quality and density compared to the other uncovered substrate. In
addition, the nanotube diameter is reduced more than half. Results also revealed that the temperature gradient played a
key factor for growth efficiency and purity of nanotubes. In addition, the diameter of CNT can be influenced by growth
temperature too. The catalyst thickness and gas flow rate were found to influence the diameter and density of tubes,
whereas the effect of synthesis time was on the CNT length. This growth technique is unique because of its simplicity,
high efficiency and its ability to yield CNTs of high purity and density. This finding is supported by Raman spectrometry
analysis.
In this paper we report the use of graphene for microwave integrated circuit transmission lines. Multi-layered
graphene films were grown on Si wafers coated with SiO2 and Ni using chemical vapour deposition. A modified
procedure to etch graphene used in our work involved the use of Au on top of graphene which formed defects
by breaking bonds of the underlying graphene, but our modified procedure enabled the etching process to be
performed with the presence of PMMA masking layer. The etchant was made of 3HCl:HNO3:8H2O. Co-planar
transmission lines of various widths and lengths were constructed on graphene to ensure compatibility with
microwave wafer probes used in the measurements.
The lines and the underlying SiO2 layer were modeled using CST Microwave Studio electromagnetic simulator.
The centre conductor width was 30 μm, while the spacing varied from 30 to 100 μm. The graphene parameters
were subsequently subtracted out from measurements by curve-fitting the experimental results with simulation.
Low frequency I-V measurements revealed conductivity of the order of 2.89 × 107 S/m, but scattering parameter
measurements of the samples conducted over 1 to 20 GHz revealed much lower conductivity, an effect which
we think was the result of poor quality thermally grown SiO2 substrates used in this experiment.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.