Ultrafast optical control of electron spin is an exciting method for writing magnetic memory with write times on the order of hundreds of femtoseconds. However, most ultrafast optical writing of magnetization has been conducted with high laser fluence (⪆ 1 mJ/cm2) which leads to excessive heating required for deterministic high-power magnetization switching. We present time-resolved magneto-optical Kerr effect observations with laser fluence 1000 times lower than previous studies, to demonstrate low-power optical control of spin in Co/Pd ultrathin multilayers. We observe clear trends between the ferromagnetic layer thickness and significant enhancement in the amplitude of optically excited magnetization precession, and demonstrate the importance of large perpendicular magnetic anisotropy for achieving high sensitivity of electron spin to low power optical excitation. Lastly, we observe a magnetization precession cone angle double of those previously reported which is an important step to achieve a 90-degree precession angle, needed for magnetization switching.
The increasing demands for device miniaturization toward energy efficient electronic, optoelectronic, and spintronic applications have led to the advancement of novel material systems such as multiferroics. In this study, we investigated nonlinear optical responses of a (0.275)BaTiO3-(0.725)BiFeO3 (BTO-BFO) film and a nanorod arrays, grown on Si substrates. Our results are important for employing these materials for new and improved optical applications.
Band structure, strain, and polarization engineering of nitride heterostructures open unparalleled opportunities for quantum sensing in the infrared. Intersubband absorption and photoluminescence are employed to correlate structure with optical properties of nonpolar strain-balanced InGaN/AlGaN nanostructures grown by molecular-beam epitaxy. Mid-infrared intersubband transitions in m-plane (In)AlxGa1-xN/In0.16Ga0.84N (0.19≤x≤0.3) multi-quantum wells were observed for the first time in the range of 3.4-5.1 μm (244-360 meV). Direct and attenuated total-reflection infrared absorption measurements are interpreted using structural information revealed by high-resolution x-ray diffraction and transmission electron microanalysis. The experimental intersubband energies are better reproduced by calculations using the local-density approximation than the Hartree-Fock approximation for the exchange-correlation correction. The effect of charge density, quantum well width, and barrier alloy composition on the intersubband transition energy was examined to evaluate the potential of this material for practical infrared applications.
Temperature-dependent continuous-wave and time-resolved photoluminescence (TRPL) measurements are also investigated to probe carrier localization and recombination in m-plane InGaN/AlGaN quantum wells. Average localization depths of 21 meV and 40 meV were estimated for the undoped and doped structures, respectively. Using TRPL, dual localization centers were identified in undoped structures, while a single type of localization centers was found in doped structures. At 2 K, a fast decay time of approximately 0.3ns was measured for both undoped and doped structures, while a longer decay time of 2.2 ns was found only for the undoped sample. TRPL in magnetic field was explored to examine the effect of doping sheets on carrier dynamics. Keywords: nitride semiconductors, intersubband absorption, photoluminescence
In this work we present PL and time resolved PL (TRPL) measurements of three of these materials: BA2PbI4, BA2MA1Pb2I7, and BA2CuCI4 where BA2 represents (CH3(CH2)3NH3)2, and MA: CH3NH3. Both BA2PbI4 and BA2CuCI4 have a single layer of perovskite material separated by an organic cation layer while BA2MA1Pb2I7 has two atomic layers of perovskite. Our observations indicate the existence of both free and trapped excitons in these systems. Additionally, BA2PbI4 displays two sets of peaks for both trapped and free excitons that evolve with temperature, indicating that as the temperature is reduced the system begins, but does not complete, a phase change from a tetragonal to an orthorhombic crystal lattice. Our result provides new insights on the low temperature behavior of this phase transition, as well as exploring the exciton spectra as a function of both temperature and magnetic field.
This material is based upon work supported by the Air Force Office of Scientific Research under awar
Co/Pd thin film multilayers show large Perpendicular Magnetic Anisotropy (PMA) which is useful in MRAM devices for perpendicular magnetic recording. Co/Pd systems have been studied extensively through the use of ultrafast optical pump-probe methods in order to measure the Time Resolved Photo-excited Precession of Magnetization (TRPEPM). Most studies have been conducted at high laser fluence (> 1 mJ/cm2), where heating near the curie temperature occurs. In this study, we present low fluence measurements between 0.42 to 3.14 μJ/cm2 in Co/Pd systems with differing Co thickness between 0.4 to 0.74 nm to probe the role of interface anisotropy in low-power excitation.
In order to accurately characterize the photoluminescence from an InAs/AlAsSb multi-quantum well hot carrier absorber, the band structure is generated with an 8 band k·p model utilizing the Naval Research Laboratory’s MultiBands® software tool. The simulated spectra for transitions between the lowest energy electron sub-band and the four lowest hole sub-bands are computed from the optical matrix elements and the calculated band structure. In depth temperature dependent simulations for absorption and photogenerated recombination of electron-hole carriers are compared with the experimental spectra. There is close agreement between simulated and observed spectra in particular, the room temperature e1-hh1 simulated transition energy of 805 meV nearly matches the 798 meV transition energy of the experimental photoluminescence spectra. Also, the expected energy separations between local maxima (p1-p2) in the simulated/experimental spectra have a difference of just 2 meV. The model has a valence band offset of 63 meV which is in general agreement with photoluminescence feature that suggests a valence band offset of 70 meV.
To analyze the ‘hot’ carriers, the photoluminescence spectra is evaluated with three different methods, a linear fit to the high energy portion of the spectra and two methods which utilize either an equilibrium or non-equilibrium generalized Planck relation to fit the whole spectrum. The non-equilibrium fit enables individual carrier temperatures for both holes and electrons. This results in two very different carrier temperatures for holes and electrons: where the hole temperature, Th, is nearly equal to the lattice temperature, TL; while, the electron temperature, Te, is ‘hot’.
β-Ga2O3 is emerging as an interesting wide band gap semiconductor for solar blind photo detectors (SBPD) and high power field effect transistors (FET) because of its outstanding material properties including an extremely wide bandgap (Eg ~4.9eV) and a high breakdown field (8 MV/cm). This review summarizes recent trends and progress in the growth/doping of β-Ga2O3 thin films and then offers an overview of the state-of-the-art in SBPD and FET devices. The present challenges for β-Ga2O3 devices to penetrate the market in real-world applications are also considered, along with paths for future work.
Ultrafast optical spectroscopy can provide insight into fundamental microscopic interactions, dynamics and the coupling of several degrees of freedom. Pump/ probe studies can reveal the answer to questions like “What are the achievable switching speeds in multiferroics?”, “What is the influence of the crystallographic orientation and domain states on the available switching states?”, and “What is the effect of the hetrostructure on promoting the coupling between the varying field excitations?”. In this presentation, we report on two color (400/800nm) ultrafast pump-probe differential reflectance spectroscopy of BiFeO3-BaTiO3 structures to probe the coupling between optical and acoustic phonons to spin waves. The data presented here is a combination of different transient reflectivity measurements to probe both the carrier and spin dynamics. The (001)-BiFeO3-BaTiO3 thin films were prepared using pulsed laser deposition on vicinal SrTiO3 substrates using La0.70 Sr0.30MnO3 bottom electrodes. Crystal orientation and topography were analyzed by x-ray diffraction and atomic force microscopy. . Our results are important to developing devices on the basis of this material system.
This work was supported by the AFOSR through grant FA9550-14-1-0376,NSF-Career Award DMR-0846834, and the Virginia Tech Institute for Critical Technology and Applied Science.
We report on the use of two-photon absorption to photocleavage o-nitrobenzyl-based ligands bound to a gold surface with thiol
groups. Ablation of ligands occurs at high power densities, but this can be largely avoided by reducing the optical power level,
at which point two-photon mediated reactions still occur on a time scale of tens of seconds. This means that photoactive ligands
can be activated at wavelengths where plasmon resonances in gold and silver nanoparticles can easily be achieved, which will
allow the surface properties at the hot spots on plasmonic nanostructures to be chosen differently from the rest of the structure,
with possible applications in high-efficiency Surface-Enhanced Raman Spectroscopy and bottom-up nanoassembly.
The recent rapid progress in the field of spintronics requires extensive studies of carrier and spin relaxation dynamics in
semiconductors. In this work, we employed time and spin resolved differential transmission measurements in order to
probe carrier and spin relaxation times in several InAsP ternary alloys. In addition, the dynamics of the excitonic
radiative transitions of InAs0.13P0.87 epitaxial layer were studied through the time-resolved photoluminescence
spectroscopy.
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