This work aimed at fabrication and electromechanical characterization of a smart material system composed of
electroactive polymer and ceramic materials. The idea of composite material system is on account of complementary
characteristics of the polymer and ceramic for flexibility and piezoelectric activity. Our preliminary work included
Polyvinylidene Fluoride (PVDF) as the flexible piezoelectric polymer, and Zinc Oxide (ZnO) as the piezoelectric
ceramic brittle, but capable to respond strains without poling. Two alternative processes were investigated. The first
process makes use of ZnO fibrous formation achieved by sintering PVA/zinc acetate precursor fibers via
electrospinning. Highly brittle fibrous ZnO mat was dipped into a PVDF polymer solution and then pressed to form
pellets. The second process employed commercial ZnO nanopowder material. The powder was mixed into a
PVDF/acetone polymer solution, and the resultant paste was pressed to form pellets. The free standing composite pellets
with electrodes on the top and bottom surfaces were then subjected to sinusoidal electric excitation and response was
recorded using a fotonic sensor. An earlier work on electrospun PVDF fiber mats was also summarized here and the
electromechanical characterization is reported.
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