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The influence of the water on the stability of complexes of 6,6′-Bis(diphenylphosphinoyl)-2,2′-bipyridyl with lanthanide ions was studied. An increase in the stability value of the complexes is observed with a decrease in the ionic radius of the metal. An increasing of the water content in acetonitrile leads to decrease the stability of the complexes. Moreover the stability of the complexes became independent on ionic radii of metals.
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Ts. Sumyanova, D. Kharitonov, A. Kharcheva, O. Farat, N. Borisova, S. Patsaeva, "The influence of water and temperature on complexes of lanthanides with 6,6′-Bis(diphenylphosphinoyl)-2,2′-bipyridyl," Proc. SPIE 11322, XIV International Conference on Pulsed Lasers and Laser Applications, 113220D (11 December 2019); https://doi.org/10.1117/12.2548826