1 August 2021Rational design of metal-free organic chromophores to form efficient room temperature persistent luminescent molecular crystals via H-bond-directed supramolecular self-assembly
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.
Long-lived room temperature ‘phosphorescence’ from organic molecular crystals has attracted great attention owing to potential applications in organic electronics, information storage, and biotechnologies. The features of the persistent luminescence strongly depend on the electronic properties of the individual molecules, and on their molecular packing in the crystal lattice. Here, a new strategy is developed by rationally designing phosphors incorporating and combining for the first time a bridge for sigma-conjugation and a moiety for H-bond-directed supramolecular self-assembly. The molecular crystals exhibit room temperature ‘phosphorescence’ quantum yields that reach up to 20% and lifetimes up to 520 ms. This study provides a promising strategy for the development of molecular crystals exhibiting efficient long-lived room temperature persistent luminescence.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.
The alert did not successfully save. Please try again later.
Catherine Demangeat, Yixuan Dou, Bin Hu, Yann Bretonniere, Chantal Andraud, Anthony D'Aleo, Jeong Weon Wu, Eunkyoung Kim, Tangui Le Bahers, André-Jean Attias, "Rational design of metal-free organic chromophores to form efficient room temperature persistent luminescent molecular crystals via H-bond-directed supramolecular self-assembly," Proc. SPIE 11808, Organic and Hybrid Light Emitting Materials and Devices XXV, 118080N (1 August 2021); https://doi.org/10.1117/12.2594420