Using two measurements in vacuum and under condition for condensing water, one might more correctly determine the true refractive index Ntrue and porosity Q with Bruggeman's EMA. The characteristics of chamber-attachment to ellipsometer, algorithm and application samples of new method for SiO2, ZrO2, HfO2, a-C:H, and In2O3-SnO2 films are presented. It is found that the differences between measurements of an effective refractive index Nef in air, in vacuum and with condensed water may be up to 0.09. The void fraction for these films are range from 0 to 0.277, Difference between Ntrue and N in air may be up to 0.036.
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