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The absorption, circular dichroism and photoinduced absorption spectra of Mn, P-doped Bi12SiO20 single crystal are studied. It is shown that dominant oxidation degree of manganese in this crystal is +4. The assignment of bands observed in studied spectra to electronic and vibronic transitions is proposed.
Anna V. Egorysheva,Vladimir I. Burkov,Yuri F. Kargin,Vitaliy M. Skorikov, andAlexander Ya. Vasil'ev
"Spectroscopic properties of Bi12SiO20 doped with (Mn,P)", Proc. SPIE 4358, Optics of Crystals, (15 March 2001); https://doi.org/10.1117/12.418836
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Anna V. Egorysheva, Vladimir I. Burkov, Yuri F. Kargin, Vitaliy M. Skorikov, Alexander Ya. Vasil'ev, "Spectroscopic properties of Bi12SiO20 doped with (Mn,P)," Proc. SPIE 4358, Optics of Crystals, (15 March 2001); https://doi.org/10.1117/12.418836