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Within the metal hard-mask (MHM) approach for contact patterning, the SiO2:TiN and SiO2:Si3N4 etch selectivities have
been studied for an Ar-C4F8-CO-based discharge in a dual-frequency capacitive coupled plasma (DFC-CCP) chamber, as
a function of gas additives and driving 2 MHz power. It is found that the O2 addition does dramatically decrease the
SiO2:TiN and SiO2:Si3N4 selectivities, while 2MHz power raises the SiO2:Si3N4 but decreases the SiO2:TiN. The
observed selectivity result from a balance between the sputtering by inert ions and the growth of a passivating
fluorocarbon film, which thickness and composition depends on the substrate nature. Selectivity is also influenced by
species kinetics at the plasma-surface interface.
J.-F. de Marneffe,F. Lazzarino,D. Goossens,Th. Conard,I. Hoflijk,D. Shamiryan,H. Struyf, andW. Boullart
"The metal hard-mask approach for contact patterning", Proc. SPIE 7521, International Conference on Micro- and Nano-Electronics 2009, 752106 (26 February 2010); https://doi.org/10.1117/12.854680
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J.-F. de Marneffe, F. Lazzarino, D. Goossens, Th. Conard, I. Hoflijk, D. Shamiryan, H. Struyf, W. Boullart, "The metal hard-mask approach for contact patterning," Proc. SPIE 7521, International Conference on Micro- and Nano-Electronics 2009, 752106 (26 February 2010); https://doi.org/10.1117/12.854680