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We report the electrical transport properties of a hybrid organic/inorganic diode device consisting of a layer of
an organic ferrimagnetic semiconductor V[TCNE]x (x~2, TCNE: tetracyanoethylene; TC ~ 400 K, EG ~ 0.5 eV, σ~ 10-2
S/cm) and a GaAs/AlGaAs p-i-n diode. Comparison with a control excluding the V[TCNE]x~2 reveals that the addition of
the V[TCNE]x~2 layer shifts the turn-on voltage and ideality of the diode in accordance with bulk V[TCNE]x~2 properties.
This result has implications for the use of inorganic systems as probes of spin physics in organic and molecular systems.
Howard Yu,Megan Harberts,Lei Fang,K. Deniz Bozdag,Chia-Yi Chen,A. J Epstein, andE. Johnston-Halperin
"Electrical transport in a hybrid organic/inorganic heterostructure", Proc. SPIE 8100, Spintronics IV, 81001E (15 September 2011); https://doi.org/10.1117/12.894641
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Howard Yu, Megan Harberts, Lei Fang, K. Deniz Bozdag, Chia-Yi Chen, A. J Epstein, E. Johnston-Halperin, "Electrical transport in a hybrid organic/inorganic heterostructure," Proc. SPIE 8100, Spintronics IV, 81001E (15 September 2011); https://doi.org/10.1117/12.894641