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Polycrystalline W03 films have been prepared which exhibit high near infrared reflectance (≈69% at 2.5μm wavelength) when lithiated. This is a significant increase in near infrared reflectance over what has been previously reported for lithiated W03. The films also exhibit a decrease in the Drude scattering parameter and a reversible structure change to higher symmetry (monoclinic to cubic) with increased lithiation. The results are consistent with models previously reported; and both the possibility of further imprvement and its significance for smart windowTM glass glass will be discussed.
R. B. Goldner,G. Seward,K. Wong,G. Berera,T. Haas, andP. Norton
"Improved Colored State Reflectivity In Lithiated WO3 Films", Proc. SPIE 0823, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VI, (12 November 1987); https://doi.org/10.1117/12.941874
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R. B. Goldner, G. Seward, K. Wong, G. Berera, T. Haas, P. Norton, "Improved Colored State Reflectivity In Lithiated WO[sub]3[/sub] Films," Proc. SPIE 0823, Optical Materials Technology for Energy Efficiency and Solar Energy Conversion VI, (12 November 1987); https://doi.org/10.1117/12.941874