We present multi-photon OLEDs where enhanced light emission was achieved by stacking
two OLEDs utilizing a regular device architecture (top cathode) and an intermediate charge
carrier generation layer (CGL) for monolithic device interconnection. With respect to future
printing processes for organic optoelectronic devices, all functional layers were deposited
from solution. The CGL comprises a low-work function zinc oxide layer that was applied
from solution under ambient conditions and at moderate processing temperatures and a high-work
function interlayer that was realized from various solution processable precursor-based
metal oxides, like molybdenum-, vanadium- and tungsten-oxide. Since every injected
electron-hole pair generates two photons, the luminance and the current efficiency of the
tandem OLED at a given device current are doubled while the power efficiency remains
constant. At a given luminance, the lower operating current in the tandem device reduces
electrical stress and improves the device life-time. ToF-SIMS, TEM/FIB and EDX analyses
provided evidence of a distinct layer sequence without intermixing upon solution deposition.
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