Transparent Conducting Oxides (TCOs) and Transition Metal Nitrides (TMNs) are emerging platforms for applications in nonlinear optics such as all-optical switching, harmonic generation and photonic time crystals and more. We report on various methods to both dynamically tune their optical properties in ultrafast time scales, and also statitcally tailor their properties. We demonstrate great control in varying the epsilon-near-zero response of TCOs such as aluminum-doped zinc oxide (AZO) and yttrium doped cadmium oxide. We also investigate the strong thickness dependence of the TCOs and TMNs optical properties. Employing the Berreman modes of TiN and AZO films on the same platform, we demonstrate variable switching speeds of an optically-pumped metasurface. We also demonstrate the nonlinear capabilities of undoped ZnO for all optical switching6 and third harmonic generation. To explore the realization of photonic time crystals, we investigate the fastest material response to an optical pump in AZO, showing sub-10 femtosecond rise time. Our approach paves the way to novel phenomena and device design with ultrafast tunable and tailorable materials.
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