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Adding a charge blocking layer at the anode of organic photodiodes suppresses the current when forward biased. This simple structure can substitute thin film transistors as a switch when scaled into an array. However, the mechanism of the structure is still unknown. Meanwhile we observe a slow turn on when reverse biased, this indicates small and large signal injection dominated by different recombination mechanisms. Here, we developed a numerical model simulating this three-layer structure and compared against experimental data to describe the carrier dynamics and elucidate the physics dominant in this switchable photodiode.
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